407704

4-Methylmorpholine

purified by redistillation, ≥99.5%

• Synonym(s): NMM
• Empirical Formula (Hill Notation): C₅H₁₁NO
• CAS Number: 109-02-4
• Molecular Weight: 101.15
• Beilstein/REAXYS Number: 102719
• EC Number: 203-640-0
• MDL number: MFCD00006175
• UNSPSC Code: 12352100
• PubChem Substance ID: 24865480
• NACRES: NA.22
• Assay: ≥99.5%
• Bp: 115-116 °C/750 mmHg (lit.)
• Vapor pressure: 18 mmHg ( 20 °C)

Properties

• vapor density: >1 (vs air)
• Quality Level: 200
• vapor pressure: 18 mmHg ( 20 °C)
• assay: ≥99.5%
• form: liquid
• purified by: glass distillation; redistillation
• refractive index: n20/D 1.435 (lit.)
• pH: 10.6 (20 °C, 50 g/L)
• bp: 115-116 °C/750 mmHg (lit.)
• mp: −66 °C (lit.)
• density: 0.92 g/mL at 25 °C (lit.)
• functional group: ether
• SMILES string: CN1CCOCC1
• InChI: 1S/C5H11NO/c1-6-2-4-7-5-3-6/h2-5H2,1H3
• InChI key: SJRJJKPEHAURKC-UHFFFAOYSA-N

Description

General description

4-Methylmorpholine is an economical cation useful for the preparation of morpholinium cation-based ionic liquids.[1] The experimental FT-IR and FT-Raman spectra of 4-methylmorpholine has been recorded over the range 4000-400cm^-1 and 3500-100cm^-1 respectively.[2] It undergoes fluorination with cobalt(III) fluoride to afford highly fluorinated morpholines, which were characterized by mass and NMR spectroscopy.[3]

Application

4-Methylmorpholine may be used in the preparation of N-ethyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide.[1]

Safety Information

• pictograms: GHS02,GHS05,GHS07
• signalword: Danger
• hcodes: H225,H302,H314
• pcodes: P210 - P233 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 1
• flash_point_f: 53.6 °F - closed cup - DIN 51755 Part 1
• flash_point_c: 12 °C - closed cup - DIN 51755 Part 1
• ppe: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter