409340

Sigma-Aldrich

Samarium(II) iodide

anhydrous, powder, ≥99.9% trace metals basis

Synonym(s):
Samarium diiodide
Linear Formula:
SmI2
CAS Number:
Molecular Weight:
404.17
MDL number:
PubChem Substance ID:
NACRES:
NA.23
Pricing and availability is not currently available.

Quality Level

grade

anhydrous

assay

≥99.9% trace metals basis

form

powder

reaction suitability

reagent type: catalyst
core: samarium

reagent type: reductant

SMILES string

I[Sm]I

InChI

1S/2HI.Sm/h2*1H;/q;;+2/p-2

InChI key

UAWABSHMGXMCRK-UHFFFAOYSA-L

Packaging

1, 5 g in ampule

Application

Promotes the cyanofluorination of aldehydes providing cyanofluorhydrins in good to excellent yield at room temperature in THF/HMPA.

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

NONH for all modes of transport

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis
Certificate of Origin
Synthesis, 1309-1309 (2007)
Martin Holan et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 21(27), 9877-9888 (2015-05-28)
Densely functionalized cyclopentane derivatives with up to four consecutive stereocenters are assembled by a tandem Michael addition/single-electron transfer oxidation/radical cyclization/oxygenation strategy mediated by ferrocenium hexafluorophosphate, a recyclable, less toxic single-electron transfer oxidant. Ester enolates were coupled with α-benzylidene and α-alkylidene...
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