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419532

2-Methylallylmagnesium chloride solution

0.5 M in THF

Synonym(s):

(2-Methyl-2-propenyl)magnesium chloride, Chloro(2-methyl-2-propenyl)magnesium, Chloro(2-methylallyl)magnesium, Methallylmagnesium chloride

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Size/SKUAvailabilityPrice
100 mL
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$234.00
$234.00
4 x 25 mL
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$236.00

About This Item

Linear Formula:
H2C=C(CH3)CH2MgCl
CAS Number:
Molecular Weight:
114.86
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:

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reaction suitability

reaction type: Grignard Reaction

Quality Segment

packaging

Sure/Seal™ of

concentration

0.5 M in THF

bp

65-67 °C

density

0.915 g/mL at 25 °C

SMILES string

CC(=C)C[Mg]Cl

InChI

1S/C4H7.ClH.Mg/c1-4(2)3;;/h1-2H2,3H3;1H;/q;;+1/p-1

InChI key

BJVFGWYBOLMUEM-UHFFFAOYSA-M

Application

2-Methylallylmagnesium chloride is a general Grignard reagent used in the synthesis of (−)-aplysin, acutumine, dimedol and allyldicyclopentadienyltitanium(III) complexes.

Packaging

The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

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This Item
773530256714
description

0.5 M in THF

description

0.5 M in THF

description

97%

reaction suitability

reaction type: Grignard Reaction

reaction suitability

reaction type: Grignard Reaction

reaction suitability

-

concentration

0.5 M in THF

concentration

0.5 M in THF

concentration

-

density

0.915 g/mL at 25 °C

density

0.933 g/mL at 25 °C

density

0.961 g/mL at 25 °C (lit.)

Quality Level

100

Quality Level

100

Quality Level

100

bp

65-67 °C

bp

-

bp

125-126 °C/50 mmHg (lit.)

packaging

Sure/Seal™ of

packaging

Sure/Seal™ of

packaging

-


Signal Word

Danger

Target Organs

Central nervous system, Respiratory system

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

Flash Point (°F)

-5.8 °F - closed cup

Flash Point (°C)

-21 °C - closed cup

PPE (personal protective equipment)

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 2

supp_hazards



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