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429120

Sigma-Aldrich

3-Methoxybenzyl bromide

98%

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Synonym(s):
1-Bromomethyl-3-methoxybenzene
Linear Formula:
CH3OC6H4CH2Br
CAS Number:
874-98-6
Molecular Weight:
201.06
MDL number:
MFCD00216590
PubChem Substance ID:
24866839
NACRES:
NA.22

Quality Level

100

Assay

98%

form

liquid

refractive index

n20/D 1.575 (lit.)

bp

152 °C (lit.)

density

1.436 g/mL at 25 °C (lit.)

SMILES string

COc1cccc(CBr)c1

InChI

1S/C8H9BrO/c1-10-8-4-2-3-7(5-8)6-9/h2-5H,6H2,1H3

InChI key

ZKSOJQDNSNJIQW-UHFFFAOYSA-N

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This Item
480622187062360082
3-Methoxybenzyl bromide 98%

Sigma-Aldrich

429120

3-Methoxybenzyl bromide

3,5-Dimethoxybenzyl bromide 95%

Sigma-Aldrich

480622

3,5-Dimethoxybenzyl bromide

3-Bromobenzyl bromide 99%

Sigma-Aldrich

187062

3-Bromobenzyl bromide

2-Phenylbenzyl bromide 97%

Sigma-Aldrich

360082

2-Phenylbenzyl bromide

form

liquid

form

-

form

solid

form

liquid

refractive index

n20/D 1.575 (lit.)

refractive index

-

refractive index

-

refractive index

n20/D 1.6280 (lit.)

bp

152 °C (lit.)

bp

-

bp

-

bp

120-125 °C/0.1 mmHg (lit.)

density

1.436 g/mL at 25 °C (lit.)

density

-

density

-

density

1.353 g/mL at 25 °C (lit.)

Quality Level

100

Quality Level

-

Quality Level

-

Quality Level

-

General description

3-Methoxybenzyl bromide is a benzyl bromide derivative.

Application

3-Methoxybenzyl bromide (1-bromomethyl-3-methoxybenzene) may be used in the diastereoselective alkylation of vicinal dianions of chiral succinic acid derivatives.
It may be used in the synthesis of the following:
  • 6-(3-methoxyphenyl)-hexane-2,4-dione
  • N-(3-methoxybenzyl)-N-(1-methyl-1-phenylethyl)-amine
  • 2-(3-methoxybenzyl)-3-[(1R)-7,7-dimethyl-2-oxobicyclo[2.2.1]hept-1-yl]-(3S)-2-thionia-bicyclo [2.2.1]- heptane tetrafluoroborate
  • 1-(3-methoxybenzyl)-5-(1-methyl-1H-imidazol-5-yl)-1H-1,2,3-triazole

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible, corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

235.4 °F - closed cup

Flash Point(C)

113 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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