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Quality Level
assay
98%
form
liquid
refractive index
n20/D 1.575 (lit.)
bp
152 °C (lit.)
density
1.436 g/mL at 25 °C (lit.)
SMILES string
COc1cccc(CBr)c1
InChI
1S/C8H9BrO/c1-10-8-4-2-3-7(5-8)6-9/h2-5H,6H2,1H3
InChI key
ZKSOJQDNSNJIQW-UHFFFAOYSA-N
Related Categories
General description
3-Methoxybenzyl bromide is a benzyl bromide derivative.
Application
3-Methoxybenzyl bromide (1-bromomethyl-3-methoxybenzene) may be used in the diastereoselective alkylation of vicinal dianions of chiral succinic acid derivatives.
It may be used in the synthesis of the following:
It may be used in the synthesis of the following:
- 6-(3-methoxyphenyl)-hexane-2,4-dione
- N-(3-methoxybenzyl)-N-(1-methyl-1-phenylethyl)-amine
- 2-(3-methoxybenzyl)-3-[(1R)-7,7-dimethyl-2-oxobicyclo[2.2.1]hept-1-yl]-(3S)-2-thionia-bicyclo [2.2.1]- heptane tetrafluoroborate
- 1-(3-methoxybenzyl)-5-(1-methyl-1H-imidazol-5-yl)-1H-1,2,3-triazole
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
wgk_germany
WGK 3
flash_point_f
closed cup
flash_point_c
closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Certificates of Analysis (COA)
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Highly diastereoselective alkylation of vicinal dianions of chiral succinic acid derivatives: a new general strategy to (R)-?-arylmethyl-?-butyrolactones.
Tetrahedron Letters, 45(22), 4315-4318 (2004)
Application of sulfur ylide mediated epoxidations in the asymmetric synthesis of ?-hydroxy-d-lactones. Synthesis of a mevinic acid analogue and (+)-prelactone B.
Tetrahedron Asymmetry, 60(43), 9725-9733 (2004)
Synthesis of (-)-kainic acid using chiral lithium amides in an asymmetric dearomatizing cyclization.
Tetrahedron, 58(23), 4727-4733 (2002)
The Journal of organic chemistry, 71(12), 4516-4520 (2006-06-06)
A mild protocol for the conversion of beta-ketoesters and beta-diketones to carboxylic acids with use of CAN in CH3CN is described. The method is compatible with a number of functional groups, and can generate carboxylic acids under neutral conditions at
The Journal of organic chemistry, 76(7), 2355-2359 (2011-03-11)
An experimentally simple sequential one-pot RuAAC reaction, affording 1,5-disubstituted 1H-1,2,3-triazoles in good to excellent yields starting from an alkyl halide, sodium azide, and an alkyne, is reported. The organic azide is formed in situ by treating the primary alkyl halide
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