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429120

Sigma-Aldrich

3-Methoxybenzyl bromide

98%

Synonym(s):

1-Bromomethyl-3-methoxybenzene

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$133.95
25 ML
$214.00

About This Item

Linear Formula:
CH3OC6H4CH2Br
CAS Number:
874-98-6
Molecular Weight:
201.06
MDL number:
MFCD00216590
UNSPSC Code:
12352100
PubChem Substance ID:
24866839
NACRES:
NA.22

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$133.95

List Price$141.00Save 5%
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In StockDetails

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Quality Level

100

assay

98%

form

liquid

refractive index

n20/D 1.575 (lit.)

bp

152 °C (lit.)

density

1.436 g/mL at 25 °C (lit.)

functional group

bromo

SMILES string

COc1cccc(CBr)c1

InChI

1S/C8H9BrO/c1-10-8-4-2-3-7(5-8)6-9/h2-5H,6H2,1H3

InChI key

ZKSOJQDNSNJIQW-UHFFFAOYSA-N

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760048529990653802
3-Methoxybenzyl bromide 98%

429120

3-Methoxybenzyl bromide

2-Chloro-4-methoxybenzyl bromide 97%

760048

2-Chloro-4-methoxybenzyl bromide

4-Bromomethyl benzoyl bromide 96%

529990

4-Bromomethyl benzoyl bromide

3-Bromophenethyl bromide 97%

653802

3-Bromophenethyl bromide

assay

98%

assay

97%

assay

96%

assay

97%

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

-

density

1.436 g/mL at 25 °C (lit.)

density

-

density

-

density

1.725 g/mL at 25 °C

bp

152 °C (lit.)

bp

-

bp

100-112 °C/0.5 mmHg (lit.)

bp

77-78 °C/0.1 mmHg

form

liquid

form

solid

form

-

form

-

refractive index

n20/D 1.575 (lit.)

refractive index

-

refractive index

-

refractive index

n20/D 1.595

General description

3-Methoxybenzyl bromide is a benzyl bromide derivative.

Application

3-Methoxybenzyl bromide (1-bromomethyl-3-methoxybenzene) may be used in the diastereoselective alkylation of vicinal dianions of chiral succinic acid derivatives.[1]
It may be used in the synthesis of the following:
  • 6-(3-methoxyphenyl)-hexane-2,4-dione[2]
  • N-(3-methoxybenzyl)-N-(1-methyl-1-phenylethyl)-amine[3]
  • 2-(3-methoxybenzyl)-3-[(1R)-7,7-dimethyl-2-oxobicyclo[2.2.1]hept-1-yl]-(3S)-2-thionia-bicyclo [2.2.1]- heptane tetrafluoroborate[4]
  • 1-(3-methoxybenzyl)-5-(1-methyl-1H-imidazol-5-yl)-1H-1,2,3-triazole[5]

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
MKCL8646
MKBT8591V
MKBL8798V
MKBF5585V
MKBF5585

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