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430269

(2-Ethyl-2-(hydroxymethyl)-1,3-propanediol polymer with (chloromethyl)oxirane

technical grade

Synonym(s):

1,3-Propanediol, 2-ethyl-2-(hydroxymethyl)-, polymer with (chloromethyl)oxirane (9CI), Epichlorohydrin-trimethylolpropane copolymer, Trimethylolpropane-epichlorohydrin copolymer

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Size/SKUAvailabilityPrice
250 mL
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$93.10
1 L
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$277.00

About This Item

Linear Formula:
(C6H14O3.C3H5ClO)x
CAS Number:
NACRES:
NA.23
UNSPSC Code:
12162002

$93.10


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grade

technical grade

Quality Segment

form

viscous liquid

eq. wt.

138-154 (perchloric acid method)

mol wt

226.70 g/mol

refractive index

n20/D 1.477 (lit.)

viscosity

120-180 cP(25 °C, Ubbelohde)(lit.)

density

1.157 g/mL at 25 °C (lit.)

SMILES string

ClCC1OC1.OCC(CO)(CC)CO

InChI

InChI=1S/C6H14O3.C3H5ClO/c1-2-6(3-7,4-8)5-9;4-1-3-2-5-3/h7-9H,2-5H2,1H3;3H,1-2H2

InChI key

HNCWRXZORGVRPD-UHFFFAOYSA-N

General description

(2-Ethyl-2-(hydroxymethyl)-1,3-propanediol polymer with (chloromethyl)oxirane has a trifunctional aliphatic glycidyl ether epoxide monomer mainly used as a crosslinking agent which provides chemical and mechanical resistance.

Application

Additive in fast-setting adhesives, low temperature curing coatings and hard, abrasion resistant castings and decoupage systems.
(2-Ethyl-2-(hydroxymethyl)-1,3-propanediol polymer with (chloromethyl)oxirane is used in the synthesis of azidated trimethylolpropane triglycidyl ether for the preparation of polyether polyol based hyperbranched polyurethanes. It can be coated on polycarbonated chips for improving chemical resistance from different organic solvents. Cross-linking of (2-Ethyl-2-(hydroxymethyl)-1,3-propanediol polymer with (chloromethyl)oxirane can be done with poly(4-venylphenol) (PVP) for the preparation of organic field effect transistors (OFETs).

Features and Benefits

Reduces viscosity but retains high epoxide level, imparts hardness and toughness to epoxide polymers. Improves solubility/compatibility characteristics of highly aromatic epoxy systems.

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This Item
1480831152825427845
description

technical grade

description

97%

description

United States Pharmacopeia (USP) Reference Standard

description

viscosity 425 cPs

grade

technical grade

grade

-

grade

pharmaceutical primary standard

grade

-

density

1.157 g/mL at 25 °C (lit.)

density

-

density

-

density

0.934 g/mL at 25 °C

viscosity

120-180 cP(25 °C, Ubbelohde)(lit.)

viscosity

-

viscosity

-

viscosity

4.0 poise(190 °C, Brookfield Thermosel)(lit.)

refractive index

n20/D 1.477 (lit.)

refractive index

-

refractive index

-

refractive index

-

mol wt

226.70 g/mol

mol wt

-

mol wt

-

mol wt

-

form

viscous liquid

form

(Powder or Crystals or Granules or Chunks)

form

-

form

beads


signalword

Danger

Hazard Classifications

Aquatic Chronic 2 - Carc. 2 - Eye Dam. 1 - Muta. 2 - Repr. 2 - Skin Corr. 1B - Skin Sens. 1

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter



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Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. 이 제품과 Trimethylolpropane triglycidyl ether의 cas no가 동일한데 Trimethylolpropane triglycidyl ether와 뭐가 다른 건가요? Trimethylolpropane triglycidyl ether를 실험에 사용하고 싶은데 이 시약을 그냥 사용하면 될까요? 아니면 사용 전 별도의 과정이 필요할까요?

    1 answer
    1. This product is a polymer made using (2-Ethyl-2-(hydroxymethyl)-1,3-propanediol) and (chloromethyl)oxirane as precursors. It has a different CAS number compared to trimethylolpropane triglycidyl ether, which has the CAS# 3454-29-3. It is advisable to test the content of trimethylolpropane triglycidyl ether in this product and purify it if necessary before further use, or use the specific reagent with the correct CAS number.

      Helpful?

  3. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

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