43158

Sigma-Aldrich

(R)-(−)-2-[2-(Diphenylphosphino)phenyl]-4-phenyl-2-oxazoline

≥97.0% (31P-NMR)

Empirical Formula (Hill Notation):
C27H22NOP
CAS Number:
Molecular Weight:
407.44
Beilstein/REAXYS Number:
7547072
MDL number:
PubChem Substance ID:

assay

≥97.0% (31P-NMR)

optical activity

[α]20/D −29.5±3°, c = 1% in chloroform

SMILES string

C1OC(=N[C@@H]1c2ccccc2)c3ccccc3P(c4ccccc4)c5ccccc5

InChI

1S/C27H22NOP/c1-4-12-21(13-5-1)25-20-29-27(28-25)24-18-10-11-19-26(24)30(22-14-6-2-7-15-22)23-16-8-3-9-17-23/h1-19,25H,20H2/t25-/m0/s1

InChI key

OKUTYUNUKKPYJS-VWLOTQADSA-N

Related Categories

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Other Notes

Chiral ligand employed in enantioselective Pd-catalyzed allylic substitution reactions

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

NONH for all modes of transport

WGK Germany

3

Certificate of Analysis

Certificate of Origin

J.M.J. Williams et al.
Tetrahedron Letters, 34, 3149-3149 (1993)
P. von Matt et al.
Angewandte Chemie (International Edition in English), 105, 614-614 (1993)

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