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432504

Sigma-Aldrich

Sodium amide

greener alternative

95%

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Synonym(s):
Sodamide
Linear Formula:
NaNH2
CAS Number:
Molecular Weight:
39.01
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

95%

form

solid

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

bp

400 °C (lit.)

mp

210 °C (lit.)

greener alternative category

SMILES string

N[Na]

InChI

1S/H2N.Na/h1H2;/q-1;+1

InChI key

ODZPKZBBUMBTMG-UHFFFAOYSA-N

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1 of 4

This Item
20832971289S8032
vibrant-m

432504

Sodium amide

-
vibrant-m

208329

Sodium amide

-
vibrant-m

71289

Sodium azide

Premium Grade
vibrant-m

S8032

Sodium azide

Premium Grade
Quality Level

100

Quality Level

200

Quality Level

200

Quality Level

200

form

solid

form

powder

form

crystals

form

powder or crystals

mp

210 °C (lit.)

mp

210 °C (lit.)

mp

-

mp

370-425 °C

bp

400 °C (lit.)

bp

400 °C (lit.)

bp

-

bp

-

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

-

greener alternative product characteristics

-

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Reagent for synthesis of:
Allylic amines and amides
Antibacterials

Reagent for:
Aggregative activation and heterocyclic chemistry
Phenylation with diphenyliodonium chloride
Sodium amide (NH2Na) (95%) can be used for a variety of applications such as:
  • production of a hydrogen storage system
  • adsorption of CO2
  • fabrication of fuel cell

pictograms

FlameCorrosion

signalword

Danger

Hazard Classifications

Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - Water-react 2

Storage Class

4.3 - Hazardous materials, which set free flammable gases upon contact with water

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Customers Also Viewed

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1 of 6

M. Bakavoli, et al.,
Journal of Heterocyclic Chemistry, 48, 149-152 (2010)
Thermal decomposition kinetics of light-weight composite NaNH2-NaBH4 hydrogen storage materials for fuel cells
Bai Y, et al.
International Journal of Hydrogen Energy, 37(17), 12973-12979 (2012)
Highly efficient CO2 adsorption by nitrogen-doped porous carbons synthesized with low-temperature sodium amide activation
Wang L, et al.
Carbon, 130(16), 31-40 (2018)
The reactions in LiBH4-NaNH2 hydrogen storage system
Zhang Y and Tian Q
International Journal of Hydrogen Energy, 36(16), 9733-9742 (2011)
Christian Bukovec et al.
Organic & biomolecular chemistry, 9(8), 2743-2750 (2011-03-08)
Stannylated allylic carbonates are suitable substrates for Pd-catalyzed allylic aminations. In DMF and with [allylPdCl](2) as catalyst the stannylated allyl amines formed can be directly coupled with electrophiles according to the Stille protocol, giving rise to highly functionalized building blocks

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