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435716

3-(Trihydroxysilyl)propyl methylphosphonate, monosodium salt solution

50 wt. % in H2O

Synonym(s):

Sodium 3-trihydroxysilylpropyl methylphosphonate

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About This Item

Linear Formula:
CH3P(O)(ONa)O(CH2)3Si(OH)3
CAS Number:
84962-98-1
Molecular Weight:
238.18
NACRES:
NA.22
PubChem Substance ID:
24867253
UNSPSC Code:
12352100
EC Number:
284-799-3
MDL number:
MFCD00274617
Form:
liquid

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InChI key

MKAWPVONNWUREJ-UHFFFAOYSA-M

InChI

1S/C4H13O6PSi.Na/c1-11(5,6)10-3-2-4-12(7,8)9;/h7-9H,2-4H2,1H3,(H,5,6);/q;+1/p-1

SMILES string

[Na+].CP([O-])(=O)OCCC[Si](O)(O)O

form

liquid

concentration

50 wt. % in H2O

impurities

4 wt. % methyl alcohol, 4 wt. % other silane-based salts, 5 wt. % sodium methyl methylphosphonate

density

1.252 g/mL at 25 °C

Quality Level

100

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1 of 4

This Item
386588F830711635
3-(Trihydroxysilyl)propyl methylphosphonate, monosodium salt solution 50 wt. % in H2O

Sigma-Aldrich

435716

3-(Trihydroxysilyl)propyl methylphosphonate, monosodium salt solution

Pinacolyl methylphosphonate 97%

Sigma-Aldrich

386588

Pinacolyl methylphosphonate

FR-900098 monosodium salt ≥97% (NMR)

Sigma-Aldrich

F8307

FR-900098 monosodium salt

Azomethine-H monosodium salt hydrate p.a.

Sigma-Aldrich

11635

Azomethine-H monosodium salt hydrate

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

form

liquid

form

liquid

form

powder

form

solid

density

1.252 g/mL at 25 °C

density

1.032 g/mL at 25 °C (lit.)

density

-

density

-

concentration

50 wt. % in H2O

concentration

-

concentration

-

concentration

-

impurities

4 wt. % methyl alcohol

impurities

-

impurities

-

impurities

-

Application

3-(Trihydroxysilyl)propyl methylphosphonate, monosodium salt was used for the following syntheses:
  • near-infrared dye-doped nanoparticles (NPs)[1]
  • as single silica source for the fabrication of phosphonate-rich organosilica layered hybrid material (PSLM)[2]
  • Gd/SiO2 nanoparticles[3]
  • mesoporous silica nanoparticles[4]
  • CdSe/ZnS/silica functionalized nanocrystals[5]

pictograms

Health hazard
GHS08

signalword

Warning

hcodes

H371

Hazard Classifications

STOT SE 2

target_organs

Eyes,Central nervous system

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

174.2 °F

flash_point_c

79 °C

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Certificates of Analysis (COA)

Lot/Batch Number
MKCZ5904
MKCT9118
MKCR0724
MKCM7548
SHBK5330

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Mesoporous silica nanoparticles facilitate delivery of siRNA to shutdown signaling pathways in mammalian cells.
Christopher Hom et al.
Small (Weinheim an der Bergstrasse, Germany), 6(11), 1185-1190 (2010-05-13)
Robert I Nooney et al.
Analytical and bioanalytical chemistry, 393(4), 1143-1149 (2008-10-11)
There is substantial interest in the development of near-infrared dye-doped nanoparticles (NPs) for a range of applications including immunocytochemistry, immunosorbent assays, flow cytometry, and DNA/protein microarray analysis. The main motivation for this work is the significant increase in NP fluorescence
Preparation and properties of various magnetic nanoparticles.
Drbohlavova J, et al.
Sensors, 9(4), 2352-2362 (2009)
Chris Daikopoulos et al.
Journal of hazardous materials, 270, 118-126 (2014-02-26)
A phosphonate-rich organosilica layered hybrid material (PSLM) made of 3-(trihydroxysilyl)propyl methylphosphonate, monosodium salt, as the single silica source, has been obtained from its aqueous solution through a xerogel process and mild thermal aging. The method is simple, affording bulk quantities
Sławomir Oszwałdowski et al.
Analytical and bioanalytical chemistry, 399(8), 2831-2842 (2011-01-27)
In the present work, CdSe nanocrystals (NCs) synthesized with a trioctylphosphine surface passivation layer were modified using amphiphilic molecules to form a surface bilayer capable of providing stable NCs aqueous solutions. Such modified nanocrystals were used as a test solute
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