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43961

Sigma-Aldrich

1-Allyl-3-methylimidazolium chloride

greener alternative

≥97.0% (HPLC)

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Synonym(s):
AMIM-Cl
Empirical Formula (Hill Notation):
C7H11ClN2
CAS Number:
65039-10-3
Molecular Weight:
158.63
MDL number:
MFCD07784450
PubChem Substance ID:
57650203
NACRES:
NA.22

Quality Level

100

Assay

≥97.0% (HPLC)

form

crystals

greener alternative product characteristics

Safer Solvents and Auxiliaries
Catalysis
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greener alternative category

Aligned

storage temp.

−20°C

SMILES string

[Cl-].C[n+]1ccn(CC=C)c1

InChI

1S/C7H11N2.ClH/c1-3-4-9-6-5-8(2)7-9;/h3,5-7H,1,4H2,2H3;1H/q+1;/p-1

InChI key

QVRCRKLLQYOIKY-UHFFFAOYSA-M

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This Item
69059727284187929
1-Allyl-3-methylimidazolium chloride ≥97.0% (HPLC)

Sigma-Aldrich

43961

1-Allyl-3-methylimidazolium chloride

1-Decyl-3-methylimidazolium chloride 96%

Sigma-Aldrich

690597

1-Decyl-3-methylimidazolium chloride

1-Ethyl-3-methylimidazolium chloride 98%

Sigma-Aldrich

272841

1-Ethyl-3-methylimidazolium chloride

1-Hexyl-3-methylimidazolium chloride ≥97.0% (HPLC)

Sigma-Aldrich

87929

1-Hexyl-3-methylimidazolium chloride

form

crystals

form

liquid

form

solid

form

liquid

storage temp.

−20°C

storage temp.

-

storage temp.

-

storage temp.

-

greener alternative product characteristics

Safer Solvents and Auxiliaries
Catalysis
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

-

greener alternative product characteristics

-

greener alternative product characteristics

-

greener alternative category

Aligned

greener alternative category

-

greener alternative category

-

greener alternative category

-

General description

1-Allyl-3-methylimidazolium chloride is a thermostable and nonvolatile task-specific ionic liquid (TSIL). It shows high cellulose solubilization ability.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

AMIM-Cl may be used:
  • As a solvent to dissolve cellulose during the preparation of regenerated cellulose materials.
  • As a solvent for the acetylation of cornhusk cellulose to form cornhusk cellulose acetates (CCAs).
  • As a plasticizer for cornstarch to form AMIM-Cl-plasticized starch film.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Ganeswar Sahu et al.
Polymers, 12(2) (2020-02-13)
This paper presents the dielectric characteristics of nanocomposite films of poly(vinyl alcohol) (PVA) embedded with silver (Ag) nanoparticles and graphene oxide(GO). The nanocomposite films were fabricated by using the solvent casting approach. The morphological analysis was carried out through scanning
Acetone-soluble cellulose acetates prepared by one-step homogeneous acetylation of cornhusk cellulose in an ionic liquid 1-allyl-3-methylimidazolium chloride (AmimCl).
Cao Y, et al.
Carbohydrate Polymers, 69(4), 665-672 (2007)
Ashna Rajeev et al.
Soft matter, 14(37), 7615-7624 (2018-08-31)
Water added to a solution of microcrystalline cellulose (MCC) in 1-allyl-3-methylimidazolium chloride (AmimCl) reduces the solvent quality and causes significant changes in the flow properties and microstructure due to restructuring and aggregation of cellulose molecules. We report an experimental investigation
1-Allyl-3-methylimidazolium chloride plasticized-corn starch as solid biopolymer electrolytes.
Ning W, et al.
Carbohydrate Polymers, 76(3), 482-484 (2009)
Tosylation and acylation of cellulose in 1-allyl-3-methylimidazolium chloride.
Granstrom M, et al.
Cellulose, 15(3), 481-488 (2008)
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Articles

Task-Specific Ionic Liquids

Task-Specific Ionic Liquids (TSILs) for the selective liquid/liquid extraction of heavy metals from aqueous systems were first published by Robin D. Rogers et al. in the year 2001.

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