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43961

1-Allyl-3-methylimidazolium chloride

greener alternative

≥97.0% (HPLC)

Synonym(s):

AMIM-Cl

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Pack SizeSKUAvailabilityPrice
5 g

Estimated to ship onMay 18, 2026fromMILWAUKEE

$93.50
50 g

Estimated to ship onMay 18, 2026fromMILWAUKEE

$370.00

About This Item

Empirical Formula (Hill Notation):
C7H11ClN2
CAS Number:
65039-10-3
Molecular Weight:
158.63
NACRES:
NA.22
PubChem Substance ID:
57650203
UNSPSC Code:
12352100
MDL number:
MFCD07784450
Assay:
≥97.0% (HPLC)
Form:
crystals

$93.50

Estimated to ship onMay 18, 2026Details

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Quality Segment

100

assay

≥97.0% (HPLC)

form

crystals

greener alternative product characteristics

Safer Solvents and Auxiliaries
Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

greener alternative category

Aligned,

storage temp.

−20°C

SMILES string

[Cl-].C[n+]1ccn(CC=C)c1

InChI

1S/C7H11N2.ClH/c1-3-4-9-6-5-8(2)7-9;/h3,5-7H,1,4H2,2H3;1H/q+1;/p-1

InChI key

QVRCRKLLQYOIKY-UHFFFAOYSA-M

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
1-Allyl-3-methylimidazolium chloride is a thermostable and nonvolatile task-specific ionic liquid (TSIL). It shows high cellulose solubilization ability.

Application

AMIM-Cl may be used:
  • As a solvent to dissolve cellulose during the preparation of regenerated cellulose materials.
  • As a solvent for the acetylation of cornhusk cellulose to form cornhusk cellulose acetates (CCAs).
  • As a plasticizer for cornstarch to form AMIM-Cl-plasticized starch film.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCN6392
BCCN0031
BCCK5967
BCCG0504
BCCD8250

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Articles

Task-Specific Ionic Liquids

Functionalized imidazolium cations with thioether, urea, or thiourea derivatized side chains act as metal-ligating moieties, whereas the PF6– anions provide the desired water immiscibility.

Acetone-soluble cellulose acetates prepared by one-step homogeneous acetylation of cornhusk cellulose in an ionic liquid 1-allyl-3-methylimidazolium chloride (AmimCl).
Cao Y, et al.
Carbohydrate Polymers, 69(4), 665-672 (2007)
Ganeswar Sahu et al.
Polymers, 12(2) (2020-02-13)
This paper presents the dielectric characteristics of nanocomposite films of poly(vinyl alcohol) (PVA) embedded with silver (Ag) nanoparticles and graphene oxide(GO). The nanocomposite films were fabricated by using the solvent casting approach. The morphological analysis was carried out through scanning
Ashna Rajeev et al.
Soft matter, 14(37), 7615-7624 (2018-08-31)
Water added to a solution of microcrystalline cellulose (MCC) in 1-allyl-3-methylimidazolium chloride (AmimCl) reduces the solvent quality and causes significant changes in the flow properties and microstructure due to restructuring and aggregation of cellulose molecules. We report an experimental investigation
View All Related Papers

Global Trade Item Number

SKUGTIN
43961-50G-F04061832246154
43961-5G-F04061832246161

Questions

1–2 of 2 Questions  

  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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