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449679

Barium isopropoxide

powder, 99% trace metals basis

Synonym(s):

Barium diisopropoxide, Barium isopropoxide, Diisopropoxybarium

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10 G

$356.00

$356.00

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About This Item

Linear Formula:
Ba(OCH(CH3)2)2
CAS Number:
24363-37-9
Molecular Weight:
255.50
NACRES:
NA.23
PubChem Substance ID:
24868500
UNSPSC Code:
12352103
MDL number:
MFCD00050486

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InChI

1S/2C3H7O.Ba/c2*1-3(2)4;/h2*3H,1-2H3;/q2*-1;+2

SMILES string

CC(C)O[Ba]OC(C)C

InChI key

CPUJSIVIXCTVEI-UHFFFAOYSA-N

assay

99% trace metals basis

form

powder, solid

reaction suitability

core: barium

mp

200 °C (dec.) (lit.)

Quality Level

100

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This Item
735787554847652458
Barium isopropoxide powder, 99% trace metals basis

Sigma-Aldrich

449679

Barium isopropoxide

Barium beads, 0.5-2.0 mm particle size, 99% trace metals basis

Sigma-Aldrich

735787

Barium

Barium oxide 99.99% trace metals basis

Sigma-Aldrich

554847

Barium oxide

Barium fluoride precipitated, 99.95% trace metals basis

Sigma-Aldrich

652458

Barium fluoride

form

powder, solid

form

beads

form

powder

form

powder

assay

99% trace metals basis

assay

99% trace metals basis

assay

99.99% trace metals basis

assay

99.95% trace metals basis

mp

200 °C (dec.) (lit.)

mp

725 °C (lit.)

mp

-

mp

-

reaction suitability

core: barium

reaction suitability

-

reaction suitability

-

reaction suitability

-

Quality Level

100

Quality Level

100

Quality Level

200

Quality Level

100

Application

For preparation of bimetallic Ba-Nb and Ba-Zr alkoxides.[1] Asymmetric aldol reactions are promoted by a novel catalyst prepared from Ba(O-i-Pr)2.[2]
It may be used as a catalyst for one pot preparation of symmetrical 1,5-diketones.[3] Sol gel synthesis of ternary compound, Ba3 Li 2Ti8 O20 can be carried out by precursor reactants, barium isopropoxide, titanium isopropoxide and lithium acetate. [4]

pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Self-heat. 2

Storage Class

4.2 - Pyrophoric and self-heating hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCM0921
MKCF3203
MKBX0763V
MKBS4808V
MKBQ0122V

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One-pot synthesis of 1,5-diketones catalyzed by barium isopropoxide
Yanagisawa A, et al.
Tetrahedron, 63.35, 8581-8585 (2007)
Preparation of YBaCuO powder by sol-gel techniques using molecular precursors.
El Khokh N, et al.
Journal of Materials Science Letters, 8.7, 762-764 (1989)
Turevskaya, E.P. et al.
Polyhedron, 14, 1531-1531 (1995)
Yamada, Y.M.A. Shibasaki, M.
Tetrahedron Letters, 39, 5561-5561 (1998)

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