453048
Dichlorobis(tri-o-tolylphosphine)palladium(II)
97%
Recommended Products
Quality Level
assay
97%
form
solid
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
core: palladium
mp
280 °C (dec.) (lit.)
SMILES string
Cl[Pd]Cl.Cc1ccccc1P(c2ccccc2C)c3ccccc3C.Cc4ccccc4P(c5ccccc5C)c6ccccc6C
InChI
1S/2C21H21P.2ClH.Pd/c2*1-16-10-4-7-13-19(16)22(20-14-8-5-11-17(20)2)21-15-9-6-12-18(21)3;;;/h2*4-15H,1-3H3;2*1H;/q;;;;+2/p-2
InChI key
OTYPIDNRISCWQY-UHFFFAOYSA-L
General description
Application
Catalyst for C-C and C-N coupling reaction.
- Reaction of tributyltin enolates, prepared in situ from tributyltin methoxide and enol acetates, with aryl bromides.
- Coupling reaction of aryl bromides with vinylic acetates.
- Negishi-Reformatsky coupling reaction of aryl bromides with ethyl 2-(tributylstannyl)acetates.
- Synthesis of (E)-methyl 3-(7-indolyl)-2-methacrylate, via Heck reaction.
- Synthesis of imidazopyrimidine derivatives.
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Certificates of Analysis (COA)
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