456411

Sigma-Aldrich

Titanium(III) chloride-aluminum chloride

TiCl3:AlCl3 3:1

Synonym(s):
Aluminum titanium chloride
Linear Formula:
(TiCl3)3 · AlCl3
CAS Number:
Molecular Weight:
596.02
EC Number:
MDL number:
PubChem Substance ID:

form

solid

composition

TiCl3:AlCl3, 3:1

reaction suitability

reagent type: catalyst
core: titanium

SMILES string

Cl[Al](Cl)Cl.Cl[Ti](Cl)Cl.Cl[Ti](Cl)Cl.Cl[Ti](Cl)Cl

InChI

1S/Al.12ClH.3Ti/h;12*1H;;;/q+3;;;;;;;;;;;;;3*+3/p-12

InChI key

DGFMFXMKCUOBCD-UHFFFAOYSA-B

Application

Low-valent titanium is a useful reducing agent in the synthesis of imidazolines.

Certificate of Analysis

Certificate of Origin

Periasamy, M. et al.
Tetrahedron Letters, 37, 4767-4767 (1996)
Atul A More et al.
Organic letters, 18(6), 1458-1461 (2016-03-08)
The first total synthesis of integrastatin B, a potent HIV-1 integrase inhibitor, has been accomplished in seven steps with a 17.9% overall yield employing easily accessible starting compounds. The Oxone-mediated oxidative benzofuran dearomatization cascade has been employed as the key...

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