458139

Sigma-Aldrich

Luperox® TBH70X, tert-Butyl hydroperoxide solution

70 wt. % in H2O

Synonym(s):
tert-Butyl hydroperoxide solution, 1,1-Dimethylethyl hydroperoxide, TBHP, 2-Hydroperoxy-2-methylpropane
Linear Formula:
(CH3)3COOH
CAS Number:
Molecular Weight:
90.12
Beilstein/REAXYS Number:
1098280
MDL number:
PubChem Substance ID:
NACRES:
NA.23

Quality Level

assay

12.25-14.20% active oxygen basis
69.0-80.0% (NH2OH, titration)

form

liquid

reaction suitability

reagent type: oxidant

concentration

70 wt. % in H2O

refractive index

n20/D 1.386

pH

4.3

bp

96.2 °C

density

0.93 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CC(C)(C)OO

InChI

1S/C4H10O2/c1-4(2,3)6-5/h5H,1-3H3

InChI key

CIHOLLKRGTVIJN-UHFFFAOYSA-N

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Application

Iron-Catalyzed Efficient Synthesis of Amides from Aldehydes and Amine Hydrochloride Salts

Iron-Catalyzed Efficient Synthesis of Amides from Aldehydes and Amine Hydrochloride Salts
Versatile reagent for oxidations.

Packaging

1, 4 L in poly bottle
18 L in poly drum
25, 100 mL in poly bottle

Legal Information

Product of Arkema Inc.
Luperox is a registered trademark of Arkema Inc.

Signal Word

Danger

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

UN 3109A1 8(5.2) / PGII

WGK Germany

WGK 3

Flash Point(F)

107.6 °F - closed cup

Flash Point(C)

42 °C - closed cup

Sci. Synth., 3, 91-131 (2004)
J. Catal., 224, 288-296 (2004)
Inorgorganica Chimica Acta, 357, 2237-2244 (2004)
J. Chem. Res. Synop., 7, 390-394 (2003)
Hsin-Yi Chen et al.
Nanoscale research letters, 13(1), 123-123 (2018-04-26)
Reactive oxygen species (ROS) have crucial roles in cell signaling and homeostasis. Overproduction of ROS can induce oxidative damage to various biomolecules and cellular structures. Therefore, developing an approach capable of monitoring and quantifying ROS in living cells is significant...

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