459097

Sigma-Aldrich

Copper(II) chloride dihydrate

99.999%

Synonym(s):
Cupric chloride dihydrate
Linear Formula:
CuCl2 · 2H2O
CAS Number:
Molecular Weight:
170.48
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.23

Quality Level

vapor density

>1 (vs air)

assay

99.999%

form

solid

impurities

≤ 15.0  ppm Trace Metal Analysis

mp

100 °C (dec.) (lit.)

Featured Industry

Battery Manufacturing

SMILES string

Cl[Cu]Cl.[H]O[H].[H]O[H]

InChI

1S/2ClH.Cu.2H2O/h2*1H;;2*1H2/q;;+2;;/p-2

InChI key

MPTQRFCYZCXJFQ-UHFFFAOYSA-L

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Application

Copper chloride dehydrate refluxed in acetonitrile can chemoselectively hydrolyze semicarbazones to carbonyl compounds. Copper chloride dehydrate may be used as a catalyst for efficiently cleaving t-butyldimethylsilyl (TBDMS).

Packaging

5 g in poly bottle

Signal Word

Danger

hazcat

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Eye Dam. 1 - Skin Irrit. 2

storage_class_code

8A - Combustible, corrosive hazardous materials

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

Certificate of Analysis

Certificate of Origin

Deprotection of t-butyldimethylsiloxy (TBDMS) protecting group with catalytic copper (II) chloride dihydrate.
Ping Z, et al.
Chinese Chemical Letters = Zhongguo Hua Xue Kuai Bao, 11(19), 753-756 (2000)
Regeneration of carbonyl compounds from semicarbazones by copper (II) chloride dihydrate.
Ram RN and Varsha K.
Tetrahedron Letters, 32(41), 5829-5832 (1991)
María S Islas et al.
Inorganic chemistry, 53(11), 5724-5737 (2014-05-16)
A new Cu(II) complex with the antihypertensive drug telmisartan, [Cu8Tlm16]·24H2O (CuTlm), was synthesized and characterized by elemental analysis and electronic, FTIR, Raman and electron paramagnetic resonance spectroscopy. The crystal structure (at 120 K) was solved by X-ray diffraction methods. The...
Bin Wu et al.
Carbohydrate research, 351, 68-73 (2012-03-01)
Two new glucoside esters 1 and 2 were produced as stress metabolites in the fresh leaves of Portulaca oleracea, in response to abiotic stress elicitation by CuCl(2). A new sugar ester (3) and two known compounds (4 and 5) were...
Iron(II)-catalyzed trifluoromethylation of potassium vinyltrifluoroborates.
Andrew T Parsons et al.
Angewandte Chemie (International ed. in English), 51(12), 2947-2950 (2012-02-14)

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