461490

Sigma-Aldrich

(R)-(+)-N,N-Dimethyl-1-(1-naphthyl)ethylamine

96%

Linear Formula:
C10H7CH(CH3)N(CH3)2
CAS Number:
Molecular Weight:
199.29
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

96%

optical activity

[α]23/D +43°, c = 2 in methanol

refractive index

n20/D 1.591 (lit.)

bp

218 °C (lit.)

density

1 g/mL at 25 °C (lit.)

SMILES string

C[C@@H](N(C)C)c1cccc2ccccc12

InChI

1S/C14H17N/c1-11(15(2)3)13-10-6-8-12-7-4-5-9-14(12)13/h4-11H,1-3H3/t11-/m1/s1

InChI key

AXRXYILTIWBHEP-LLVKDONJSA-N

Related Categories

Application

(R)-(+)-N,N-Dimethyl-1-(1-naphthyl)ethylamine can react with palladium acetate in acetic acid to form cyclopalladated naphthyl adduct.
Base for kinetic resolution of alcohols and acyl halides.

Packaging

1 g in glass bottle

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Precautionary Statements

Target Organs

Respiratory system

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

NONH for all modes of transport

WGK Germany

WGK 3

Flash Point(F)

235.4 °F - closed cup

Flash Point(C)

113 °C - closed cup

Certificate of Analysis

Certificate of Origin

Optically active cyclopalladated compounds containing P-chiral ligands. Restricted rotation around the Pd? P bond.
Albert J, et al.
Journal of Organometallic Chemistry, 634(1), 83-89 (2001)
Weidert, P.J. et al.
Liebigs Ann. Chem., 533-533 (1989)

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