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461490

Sigma-Aldrich

(R)-(+)-N,N-Dimethyl-1-(1-naphthyl)ethylamine

96%

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Linear Formula:
C10H7CH(CH3)N(CH3)2
CAS Number:
Molecular Weight:
199.29
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

96%

optical activity

[α]23/D +43°, c = 2 in methanol

refractive index

n20/D 1.591 (lit.)

bp

218 °C (lit.)

density

1 g/mL at 25 °C (lit.)

SMILES string

C[C@@H](N(C)C)c1cccc2ccccc12

InChI

1S/C14H17N/c1-11(15(2)3)13-10-6-8-12-7-4-5-9-14(12)13/h4-11H,1-3H3/t11-/m1/s1

InChI key

AXRXYILTIWBHEP-LLVKDONJSA-N

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2-(Ethylthio)ethylamine 96%

638501

2-(Ethylthio)ethylamine

bp

218 °C (lit.)

bp

140-142 °C (lit.)

bp

159-160 °C/760 mmHg (lit.)

bp

-

refractive index

n20/D 1.591 (lit.)

refractive index

n20/D 1.4283 (lit.)

refractive index

n20/D 1.4900

refractive index

-

density

1 g/mL at 25 °C (lit.)

density

0.793 g/mL at 25 °C (lit.)

density

0.946 g/mL at 25 °C

density

-

optical activity

[α]23/D +43°, c = 2 in methanol

optical activity

-

optical activity

-

optical activity

-

Application

(R)-(+)-N,N-Dimethyl-1-(1-naphthyl)ethylamine can react with palladium acetate in acetic acid to form cyclopalladated naphthyl adduct.
Base for kinetic resolution of alcohols and acyl halides.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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Optically active cyclopalladated compounds containing P-chiral ligands. Restricted rotation around the Pd? P bond.
Albert J, et al.
Journal of Organometallic Chemistry, 634(1), 83-89 (2001)
Weidert, P.J. et al.
Liebigs Ann. Chem., 533-533 (1989)

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