463353

Sigma-Aldrich

tert-Butyl methacrylate

98%, contains 200 ppm monomethyl ether hydroquinone as inhibitor

Synonym(s):
Acryester TB, tert -Butyl α-methacrylate, 1,1-Dimethylethyl methacrylate, tert -Butyl methacrylate
Linear Formula:
H2C=C(CH3)CO2C(CH3)3
CAS Number:
Molecular Weight:
142.20
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.23
Pricing and availability is not currently available.

Quality Level

assay

98%

contains

200 ppm monomethyl ether hydroquinone as inhibitor

refractive index

n20/D 1.415 (lit.)

bp

132 °C (lit.)

density

0.875 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

CC(=C)C(=O)OC(C)(C)C

InChI

1S/C8H14O2/c1-6(2)7(9)10-8(3,4)5/h1H2,2-5H3

InChI key

SJMYWORNLPSJQO-UHFFFAOYSA-N

Related Categories

Application

tert-Butyl methacrylate (tert-BMA) can be used in the formation of homo and block copolymers by atom transfer radical polymerization (ATRP) for potential usage in coatings, biomaterials and flocculants.

Packaging

100, 250 mL in glass bottle

Pictograms

FlameExclamation mark

Signal Word

Warning

Hazard Statements

Target Organs

Respiratory system

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

UN 3272 3 / PGIII

WGK Germany

WGK 1

Flash Point(F)

86.0 °F - closed cup

Flash Point(C)

30 °C - closed cup

Phase behavior of linear polystyrene-block-poly (2-vinylpyridine)-block-poly (tert-butyl methacrylate) triblock terpolymers
Ludwigs S, et al.
Polymer, 44(22), 6815-6823 (2003)
Termination Kinetics of tert-Butyl Methacrylate and of n-Butyl Methacrylate Free-Radical Bulk Homopolymerizations
Buback M and Junkers T
Macromolecular Chemistry and Physics, 207(18), 1640-1650 (2006)
Homo and block copolymers of tert-butyl methacrylate by atom transfer radical polymerization
Krishnan R and Srinivasan KSV
European Polymer Journal, 40(10), 2269-2276 (2004)
Hironori Kumagai et al.
European journal of pharmaceutics and biopharmaceutics : official journal of Arbeitsgemeinschaft fur Pharmazeutische Verfahrenstechnik e.V, 136, 29-37 (2019-01-15)
We are investigating an imaging agent for early detection of colorectal cancer. The agent, named the nanobeacon, is coumarin 6-encapsulated polystyrene nanospheres whose surfaces are covered with poly(N-vinylacetamide) and peanut agglutinin that reduces non-specific interactions with the normal mucosa and...
Yue Liu et al.
Colloids and surfaces. B, Biointerfaces, 136, 721-728 (2015-10-30)
A novel nanoparticle with multilayer core-shell architecture for cell imaging is designed and synthesized by coating a fluorescent YVO4:Eu core with a diblock copolymer, MPEG-b-PMAA. The synthesis of YVO4:Eu core, which further makes MPEG-b-PMAA-YVO4:Eu NPs adapt for cell imaging, is...

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