464872

Lithium diphenylphosphide solution

0.5 M in THF

• Synonym(s): Diphenyl lithium phosphide, Diphenylphosphine lithium salt, Diphenylphosphino)lithium, Lithiodiphenyl phosphide, Lithiodiphenylphosphine
• Linear Formula: (C₆H₅)₂PLi
• CAS Number: 65567-06-8
• Molecular Weight: 192.12
• NACRES: NA.22
• PubChem Substance ID: 24870228
• UNSPSC Code: 12352002
• MDL number: MFCD00046054

Properties

• Quality Segment: 100
• reaction suitability: reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
• concentration: 0.5 M in THF
• bp: 65-67 °C
• density: 0.925 g/mL at 25 °C
• SMILES string: [Li]P(c1ccccc1)c2ccccc2
• InChI: 1S/C12H10P.Li/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10H;/q-1;+1
• InChI key: WKUYEGHEUWHKIU-UHFFFAOYSA-N

Description

Safety Information

• pictograms: GHS02,GHS08,GHS05,GHS07,GHS09
• signalword: Danger
• supp_hazards: EUH019
• Storage Class: 3 - Flammable liquids
• flash_point_f: -4.0 °F - closed cup
• flash_point_c: -20 °C - closed cup
• ppe: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
• hcodes: H225,H302,H314,H335,H336,H351,H410
• pcodes: P210 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
• target_organs: Central nervous system, Respiratory system