473235

Sigma-Aldrich

N,N-Diethylhydroxylamine solution

85 wt. % in H2O

Linear Formula:
(C2H5)2NOH
CAS Number:
Molecular Weight:
89.14
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

concentration

85 wt. % in H2O

refractive index

n20/D 1.419

bp

125-130 °C

mp

−25 °C

density

0.902 g/mL at 25 °C

SMILES string

CCN(O)CC

InChI

1S/C4H11NO/c1-3-5(6)4-2/h6H,3-4H2,1-2H3

InChI key

FVCOIAYSJZGECG-UHFFFAOYSA-N

General description

The product is 85wt.% solution of N,N-diethylhydroxylamine. The reaction of N,N-diethylhydroxylamine with tert-butylhydroperoxide has been studied. It participates in the preparation of symmetrical and an isomeric mixture of unsymmetrical phthalocyanines. It undergoes degradation on exposure to radiation and affords light hydrocarbons. Qualitative and quantitative analyses of the produced hydrocarbons have been reported. It also participates in the conversion of quinones and quinonemonosulfonimide to the corresponding hydroquinones and sulfonylaminophenols, respectively.

Packaging

250 g in glass bottle
2 kg in glass bottle

Pictograms

FlameExclamation mark

Signal Word

Warning

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

UN 1993C 3 / PGIII

WGK Germany

WGK 1

Flash Point(F)

113.0 °F - closed cup

Flash Point(C)

45 °C - closed cup

Qualitative and quantitative analysis of the light hydrocarbons produced by radiation degradation of N, N-diethylhydroxylamine.
Wang J, et al.
J. Radioanal. Nucl. Chem., 262(2), 451-453 (2004)
Oxidation of N, N-dialkyl hydroxylamines with t-butyl hydroperoxide. A new synthesis for nitrones.
Mare HDL and Coppinger GM.
The Journal of Organic Chemistry, 28(4), 1068-1070 (1963)
Reduction of quinones and quinonemonosulfonimides with N, N-diethylhydroxylamine.
Fujita S and Sano K.
The Journal of Organic Chemistry, 44(15), 2647-2651 (1979)
Novel and Mild Route to Phthalocyanines and 3-Iminoisoindolin-1-ones via N, N-Diethylhydroxylamine-Promoted Conversion of Phthalonitriles and a Dramatic Solvent-Dependence of the Reaction.
Luzyanin KV, et al.
Advanced Synthesis & Catalysis, 350(1), 135-142 (2008)
Gino A DiLabio et al.
Physical chemistry chemical physics : PCCP, 9(13), 1629-1634 (2007-04-13)
Incorporating diversity into structures constructed from the organic modification of silicon surfaces requires the use of molecules that contain multiple substituents of different types. In this work we examine the possible dissociation pathways of diethylhydroxylamine (DEHA, (C(2)H(5))(2)NOH) on the surface...

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