47718

(Formylmethyl)triphenylphosphonium chloride

≥97.0% (AT)

• Synonym(s): 2-Oxoethyltriphenylphosphonium chloride
• Linear Formula: HCOCH₂P(Cl)(C₆H₅)₃
• CAS Number: 62942-43-2
• Molecular Weight: 340.78
• UNSPSC Code: 12352114
• NACRES: NA.22
• PubChem Substance ID: 24871339
• EC Number: 263-767-2
• Beilstein/REAXYS Number: 4060813
• MDL number: MFCD00012003
• Assay: ≥97.0% (AT)
• Form: solid

Properties

• Quality Segment: 100
• assay: ≥97.0% (AT)
• form: solid
• reaction suitability: core: phosphonium, reaction type: C-C Bond Formation, reaction type: phase-transfer
• mp: 209-212 °C (dec.) (lit.)
• functional group: aldehyde, phosphine
• storage temp.: 2-8°C
• SMILES string: [Cl-].O=CC[P+](c1ccccc1)(c2ccccc2)c3ccccc3
• InChI: 1S/C20H18OP.ClH/c21-16-17-22(18-10-4-1-5-11-18,19-12-6-2-7-13-19)20-14-8-3-9-15-20;/h1-16H,17H2;1H/q+1;/p-1
• InChI key: RVEJRPJGKXTQIF-UHFFFAOYSA-M

Description

Application

Reactant for:

• Hydroazidation reactions in preparation of a-azido alcohols
• Preparation of prodrug (2-hydroxyamino-vinyl)-triphenyl-phosphonium (HVTP) inhibitor of peroxidase activity and apoptosis
• Intramolecular [4 + 3] cycloaddition reactions

Safety Information

• Pictograms: GHS05,GHS07
• Signal Word: Danger
• Hazard Codes: H302,H318
• Precautionary Statements: P264 - P270 - P280 - P301 + P312 - P305 + P351 + P338 - P501
• Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1
• Storage Class: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• PPE (personal protective equipment): dust mask type N95 (US), Eyeshields, Gloves