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481548

Sigma-Aldrich

Lithium trifluoromethanesulfonate

greener alternative

99.995% trace metals basis

Synonym(s):
Trifluoromethanesulfonic acid lithium salt, LiTf, Lithium triflate
Linear Formula:
CF3SO3Li
CAS Number:
Molecular Weight:
156.01
Beilstein:
4301818
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.23

Quality Level

assay

99.995% trace metals basis

form

powder

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

impurities

≤60  ppm Trace Metal Analysis

mp

>300 °C (lit.)

Featured Industry

Battery Manufacturing

greener alternative category

Enabling

SMILES string

[Li+].[O-]S(=O)(=O)C(F)(F)F

InChI

1S/CHF3O3S.Li/c2-1(3,4)8(5,6)7;/h(H,5,6,7);/q;+1/p-1

InChI key

MCVFFRWZNYZUIJ-UHFFFAOYSA-M

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.
Lithium trifluoromethanesulfonate is a class of electrolytic materials that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.

Application

LiOTf can be used for a variety of applications such as:
  • a polymeric layer for light-emitting electrochemical cells
  • an electrolyte for lithium-ion batteries
  • a recyclable catalyst for acetylation of alcohols and diacetylation of aldehydes
  • a separator for supercapacitors

Packaging

5, 25 g in poly bottle

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Precautionary Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

Certificate of Analysis

Certificate of Origin

Polymer light-emitting electrochemical cells: Doping, luminescence, and mobility
Edman L, et al.
Physical Review. B, Condensed Matter and Materials Physics, 70(11), 115212-115212 (2004)
An improved high-performance lithium-air battery
Jung H, et al.
Nature Chemistry, 4(7), 579-579 (2012)
Soo, P.P.; Huang, B.; Jang, Y.-I.; Chiang, Y.-M.; Sadoway, D.R.; Mayes, A.M.
Journal of the Electrochemical Society, 146, 32-32 (1999)
Lithium trifluoromethanesulfonate (LiOTf) as a recyclable catalyst for highly efficient acetylation of alcohols and diacetylation of aldehydes under mild and neutral reaction conditions
Karimi B and Maleki J
The Journal of Organic Chemistry, 68(12), 4951-4954 (2003)
Development of all-solid-state mediator-enhanced supercapacitors with polyvinylidene fluoride/lithium trifluoromethanesulfonate separators
Zhou J, et al.
Journal of Power Sources, 196(23), 10479-10483 (2011)

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