491748

4-(Bromomethyl)pyridine hydrobromide

97%

• Synonym(s): (4-Pyridyl)methyl bromide hydrobromide, 4-(Bromomethyl)pyridine monohydrobromide, 4-Picolyl bromide hydrobromide
• Empirical Formula (Hill Notation): C₆H₆BrN · HBr
• CAS Number: 73870-24-3
• Molecular Weight: 252.93
• NACRES: NA.22
• PubChem Substance ID: 24872681
• UNSPSC Code: 12352100
• MDL number: MFCD01863545
• Assay: 97%

Properties

• Quality Segment: 100
• assay: 97%
• mp: 189-192 °C (lit.)
• functional group: bromo
• SMILES string: Br[H].BrCc1ccncc1
• InChI: 1S/C6H6BrN.BrH/c7-5-6-1-3-8-4-2-6;/h1-4H,5H2;1H
• InChI key: VAJUUDUWDNCECT-UHFFFAOYSA-N

Description

General description

4-(Bromomethyl)pyridine hydrobromide is a substituted pyridine. It reacts with 1,2-ethanediamine and 1,3-propanediamine to form the corresponding diamines.[1]

Application

4-(Bromomethyl)pyridine hydrobromide may be used in the preparation of:

• 3-(4-pyridylmethyl)-2′,3′-di-O-oleyl-5′-O-(4,4′-dimethoxytriphenylmethyl)uridine[2]
• 3-(4-pyridylmethyl)-3′-O-oleyl-5′-O-(4,4-dimethoxytriphenylmethyl)-thymidine[2]
• 1,4-bis(N-hexyl-4-pyridinium)butadiene diperchlorate

It may also be used in the preparation of the following benzoxazine derivatives:[3]

• 2-morpholin-4-yl-7-(pyridin-4-ylmethoxy)-4H-1,3-benzoxazin-4-one
• 8-methyl-2-morpholin-4-yl-7-(pyridin-4-ylmethoxy)-4H-1,3-benzoxazin-4-one
• 2-morpholin-4-yl-8-(pyridin-4-ylmethoxy)-4H-1,3-benzoxazin-4-one

Safety Information

• pictograms: GHS05
• signalword: Danger
• hcodes: H314
• pcodes: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
• Hazard Classifications: Skin Corr. 1B
• Storage Class: 8A - Combustible corrosive hazardous materials
• wgk: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges