- 498033
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498033
Cyclohexylzinc bromide solution
0.5 M in THF
All Photos(1)
Linear Formula:
C6H11ZnBr
CAS Number:
Molecular Weight:
228.45
MDL number:
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
concentration
0.5 M in THF
density
0.963 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
Br[Zn]C1CCCCC1
InChI
1S/C6H11.BrH.Zn/c1-2-4-6-5-3-1;;/h1H,2-6H2;1H;/q;;+1/p-1
InChI key
XHGMTEIVIUFIPO-UHFFFAOYSA-M
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This Item | 497908 | 520292 | 520233 |
|---|---|---|---|
| density 0.963 g/mL at 25 °C | density 0.955 g/mL at 25 °C | density 0.98 g/mL at 25 °C | density 0.979 g/mL at 25 °C |
| storage temp. 2-8°C | storage temp. 2-8°C | storage temp. 2-8°C | storage temp. 2-8°C |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| concentration 0.5 M in THF | concentration 0.5 M in THF | concentration 0.5 M in THF | concentration 0.5 M in THF |
Application
Cyclohexylzinc bromide is an organozinc reagent, generally used in Negishi coupling. Examples include the cross-coupling of alkylzinc halides with aryl/heteroaryl halides using Pd-PEPPSI-IPent and nickel-catalyzed synthesis of 4-substituted coumarins.
It can react with the SO2 surrogate, 1,4-diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct (DABSO) to afford zinc sulfinate salts which can be alkylated to synthesize various useful sulfones.
It can react with the SO2 surrogate, 1,4-diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct (DABSO) to afford zinc sulfinate salts which can be alkylated to synthesize various useful sulfones.
Legal Information
Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
Supplementary Hazards
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
3.0 °F - closed cup
Flash Point(C)
-16.1 °C - closed cup
Certificate of Analysis
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Certificate of Origin
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