498815

(S)-(−)-3-Methoxy-2-methyl-3-oxopropylzinc bromide solution

0.5 M in THF

• Linear Formula: CH₃O₂CCH(CH₃)CH₂ZnBr
• CAS Number: 312693-18-8
• Molecular Weight: 246.42
• MDL number: MFCD00671994
• PubChem Substance ID: 24873228
• NACRES: NA.22

Properties

• Quality Level: 100
• concentration: 0.5 M in THF
• density: 0.965 g/mL at 25 °C
• storage temp.: 2-8°C
• SMILES string: COC(=O)[C@H](C)C[Zn]Br
• InChI: 1S/C5H9O2.BrH.Zn/c1-4(2)5(6)7-3;;/h4H,1H2,2-3H3;1H;/q;;+1/p-1/t4-;;/m0../s1
• InChI key: ZYPPBSJLXDMOPY-FHNDMYTFSA-M

Description

Application

(S)-(−)-3-Methoxy-2-methyl-3-oxopropylzinc bromide can be used:

• As an intermediate in the total synthesis of macrolide derivative laingolide B stereoisomers.
• As a substrate in the synthesis of (3R)-1-benzyl-3-methylpyrrolidine-2,5-dione (aliphatic carboxamide) using Ni^II-pincer complexes.

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Safety Information

• Pictograms: GHS02,GHS07,GHS08
• Signal Word: Danger
• Hazard Statements: H225 - H261 - H302 - H319 - H335 - H336 - H351
• Precautionary Statements: P201 - P210 - P231 + P232 - P301 + P312 - P305 + P351 + P338 - P308 + P313
• Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Water-react 2
• Supplementary Hazards: EUH018 - EUH019
• Storage Class Code: 4.3 - Hazardous materials, which set free flammable gases upon contact with water
• WGK: WGK 3
• Flash Point(F): 1.4 °F - closed cup
• Flash Point(C): -17 °C - closed cup