Glycidyl propargyl ether

Name: Glycidyl propargyl ether
Brand: ALDRICH
Price: 164.25 USD
Availability: InStock

technical, ≥90% (GC)

Synonym(s):

2,3-Epoxypropyl propargyl ether

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About This Item

Empirical Formula (Hill Notation):

C₆H₈O₂

CAS Number:

18180-30-8

Molecular Weight:

112.13

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

57651238

MDL number:

MFCD00099300

Beilstein/REAXYS Number:

1098793

Assay:

≥90% (GC)

Key Documents

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InChI

1S/C6H8O2/c1-2-3-7-4-6-5-8-6/h1,6H,3-5H2

SMILES string

C#CCOCC1CO1

InChI key

SYFZCLMMUNCHNH-UHFFFAOYSA-N

grade

technical

assay

≥90% (GC)

refractive index

n20/D 1.448

density

1.040 g/mL at 20 °C (lit.)

functional group

ether

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This Item	148067	473642	291463
Sigma-Aldrich 50062 Glycidyl propargyl ether	Sigma-Aldrich 148067 Glycidyl 4-methoxyphenyl ether	Sigma-Aldrich 473642 Glycidyl hexadecyl ether	Sigma-Aldrich 291463 Glycidyl isopropyl ether
assay ≥90% (GC)	assay 99%	assay -	assay 98%
density 1.040 g/mL at 20 °C (lit.)	density -	density -	density 0.924 g/mL at 25 °C (lit.)
refractive index n20/D 1.448	refractive index -	refractive index -	refractive index n20/D 1.410 (lit.)
grade technical	grade -	grade -	grade -
functional group ether	functional group -	functional group -	functional group -

General description

Glycidyl propargyl ether (GPE) is a glycidyl ether containing a terminal alkyne group.

Application

Glycidyl propargyl ether may be used in the synthesis of:

propargyl-functional poly(carbonate)s[1]
hyperbranched polyglycerol (hbPG)[2]
alkyne-functionalized polytetrahydrofuran (PTHF) diols[3]
dextran-based cyclodextrin polymers[4]

pictograms

GHS08,GHS07

signalword

Danger

hcodes

H332,H334,H350

pcodes

P202 - P261 - P271 - P280 - P284 - P308 + P313

Hazard Classifications

Acute Tox. 4 Inhalation - Carc. 1B - Resp. Sens. 1

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

156.2 °F - closed cup

flash_point_c

69 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Dextran-based cyclodextrin polymers: their solubilizing effect and self-association.

Zoltán Fülöp et al.

Carbohydrate polymers, 97(2), 635-642 (2013-08-06)

Cyclodextrins and their water-soluble derivatives are excellent solubilizers and stabilizers and widely used as enabling pharmaceutical excipients. However, still new cyclodextrin derivatives are being designed and synthesized in an effort to improve their physicochemical properties. In this study physicochemical and

Combining cationic ring-opening polymerization and click chemistry for the design of functionalized polyurethanes.

Basko M, et al.

Journal of Polymer Science Part A: Polymer Chemistry, 49(7), 1597-1604 (2011)

Propargyl-Functional Aliphatic Polycarbonate Obtained from Carbon Dioxide and Glycidyl Propargyl Ether.

Hilf J and Frey H.

Macromolecular Rapid Communications, 34(17), 1395-1400 (2013)

One-step synthesis of multi-alkyne functional hyperbranched polyglycerols by copolymerization of glycidyl propargyl ether and glycidol.

Schull C, et al.

Polym. Chem., 4(17), 4730-4736 (2013)

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