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510866

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Poly(3-dodecylthiophene-2,5-diyl)

regiorandom

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Synonym(s):
P3DDT
CAS Number:
MDL number:
NACRES:
NA.23

mol wt

average Mn 30,000
average Mw 70,000

solubility

chloroform, methylene chloride, toluene, and THF: soluble

fluorescence

λex 416 nm; λem 545 nm in chloroform

OPV device performance

ITO/PEDOT:PSS/P3DDT/PC61BM (1:3)/LiF/Al

  • Short-circuit current density (Jsc): 2.9 mA/cm2
  • Open-circuit voltage (Voc): 0.6 V
  • Fill Factor (FF): 0.38
  • Power Conversion Efficiency (PCE): 0.65 %

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495344450650495336
Poly(3-dodecylthiophene-2,5-diyl) regiorandom

510866

Poly(3-dodecylthiophene-2,5-diyl)

Poly(3-decylthiophene-2,5-diyl) regioregular, average Mw ~42,000, average Mn ~30,000

495344

Poly(3-decylthiophene-2,5-diyl)

Poly(3-dodecylthiophene-2,5-diyl) regioregular, average Mw ~60,000

450650

Poly(3-dodecylthiophene-2,5-diyl)

Poly(3-butylthiophene-2,5-diyl) regioregular

495336

Poly(3-butylthiophene-2,5-diyl)

solubility

chloroform, methylene chloride, toluene, and THF: soluble

solubility

-

solubility

chloroform: soluble

solubility

chlorinated solvents: soluble (partially soluble in THF, diethylether)

fluorescence

λex 416 nm; λem 545 nm in chloroform

fluorescence

λex 441 nm; λem 567 nm in chloroform

fluorescence

λex 442 nm; λem 568 nm in chloroform

fluorescence

λex 440 nm; λem 567 nm in chloroform

OPV device performance

ITO/PEDOT:PSS/P3DDT/PC61BM (1:3)/LiF/Al

  • Short-circuit current density (Jsc): 2.9 mA/cm2
  • Open-circuit voltage (Voc): 0.6 V
  • Fill Factor (FF): 0.38
  • Power Conversion Efficiency (PCE): 0.65 %

OPV device performance

-

OPV device performance

ITO/PEDOT:PSS/P3DDT/PC61BM (1:3)/LiF/Al

  • Short-circuit current density (Jsc): 2.9 mA/cm2
  • Open-circuit voltage (Voc): 0.6 V
  • Fill Factor (FF): 0.38
  • Power Conversion Efficiency (PCE): 0.65 %

OPV device performance

-

General description

Poly(3-dodecylthiophene-2,5-diyl) (P3DDT) is a poly(3-alkylthiophene) based conducting polymer that shows reversible electrochemistry with high conductivity. It is a regioregular polymer that can be used in the development of a variety of organic electronics based devices.

Application

P3DDT can be used as a conjugating polymer in the fabrication of electrochemical devices, which include polymeric solar cells, chemical sensors and field effect transistors.
This material has solid state properties. Rechargeable battery electrodes, electrochromic devices, chemical and optical sensors, light-emitting diodes, microelectrical amplifiers, field-effect transistors and non-linear optical materials.
Conducting polymer.
Rechargeable battery electrodes, electrochromic devices, chemical and optical sensors, light-emitting diodes, microelectrical amplifiers, field-effect transistors and non-linear optical materials.

Packaging

Packaged in glass bottles

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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Journal of the American Chemical Society, 117, 233-233 (1994)
Inkjet printed chemical sensor array based on polythiophene conductive polymers
Li B, et al.
Sensors and Actuators B, Chemical, 123(2), 651-660 (2007)
Evaluation of solution-processable carbon-based electrodes for all-carbon solar cells
Ramuz MP, et al.
ACS Nano, 6(11), 10384-10395 (2012)
Self-orienting head-to-tail poly (3-alkylthiophenes): new insights on structure-property relationships in conducting polymers
McCullough RD, et al.
Journal of the American Chemical Society, 115(11), 4910-4911 (1993)
Evidence of a novel side chain structure in regioregular poly (3-alkylthiophenes)
Prosa TJ, et al.
Macromolecules, 29(10), 3654-3656 (1996)

Articles

Intrinsically stretchable active layers for organic field-effect transistors (OFET) are discussed. Polymer structural modification & post-polymerization modifications are 2 methods to achieve this.

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