5,5′-Dimethyl-2,2′-dipyridyl

Name: 5,5′-Dimethyl-2,2′-dipyridyl
Brand: ALDRICH
Price: 116 USD

98%

Synonym(s):

5,5′-Dimethyl-2,2′-bipyridine

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About This Item

Empirical Formula (Hill Notation):

C₁₂H₁₂N₂

CAS Number:

1762-34-1

Molecular Weight:

184.24

MDL number:

MFCD01740554

UNSPSC Code:

12352100

PubChem Substance ID:

24873670

NACRES:

NA.22

Key Documents

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Quality Level

100

assay

98%

mp

114-117 °C (lit.)

SMILES string

Cc1ccc(nc1)-c2ccc(C)cn2

InChI

1S/C12H12N2/c1-9-3-5-11(13-7-9)12-6-4-10(2)8-14-12/h3-8H,1-2H3

InChI key

PTRATZCAGVBFIQ-UHFFFAOYSA-N

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This Item	569593	245739	742481
Sigma-Aldrich 513040 5,5′-Dimethyl-2,2′-dipyridyl	Sigma-Aldrich 569593 4,4′-Dimethyl-2,2′-dipyridyl	Sigma-Aldrich 245739 4,4′-Dimethyl-2,2′-dipyridyl	Sigma-Aldrich 742481 Dimethyl 2,2′-bipyridine-4,4′-dicarboxylate
assay 98%	assay 99.5%	assay 99%	assay ≥98.0% (HPLC)
Quality Level 100	Quality Level 100	Quality Level 200	Quality Level 100
mp 114-117 °C (lit.)	mp 169-174 °C (lit.)	mp 169-174 °C (lit.)	mp 208-212 °C

pictograms

GHS07

signalword

Warning

hcodes

H302,H315,H319,H335

pcodes

P261 - P264 - P271 - P301 + P312 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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New Organometallic Ruthenium(II) Compounds Synergistically Show Cytotoxic, Antimetastatic and Antiangiogenic Activities for the Treatment of Metastatic Cancer.

Yuchen Wang et al.

Chemistry (Weinheim an der Bergstrasse, Germany), 26(66), 15170-15182 (2020-07-09)

In this study, we newly designed and synthesized a small library of ten structurally related C,N-cyclometalated ruthenium(II) complexes containing various pyridine-functionalized NHC ligand and chelating bipyridyl ligands (e.g., 2,2'-bipyridine, 5,5'-dimethyl-2,2'-bipyridine, and 1,10-phenanthroline (phen)). The complexes were well characterized by NMR

Synthesis, characterization and crystal structure determination of iron (III) hetero-ligand complexes containing 2, 2'-bipyridine, 5, 5'-dimethyl-2, 2'-bipyridine and chloride, [Fe(bipy)Cl₄][bipy?H] and [Fe(dmbipy)₂Cl₂][FeCl₄].

Amani V, et al.

Polyhedron, 26(15), 4257-4262 (2007)

Aromatic versus Aliphatic α-Diimine Ligands in Heteroleptic Copper(I) Emitters: Photophysical and Electrochemical Properties.

Masaki Yoshida et al.

Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 36(1), 67-73 (2019-11-07)

The electrochemical and photophysical properties of a heteroleptic Cu(I) complex bearing an aliphatic α-diimine ligand, [Cu(dab)(xantphos)]+ (Cu-dab; dab = N,N'-diphenyl-2,3-dimethyl-1,4-diazabutadiene, xantphos = 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene), were evaluated together with those of complexes [Cu(dmp)(xantphos)]+ (Cu-dmp; dmp = 2,9-dimethyl-1,10-phenanthroline), [Cu(dmbpy)(xantphos)]+ (Cu-dmbpy; dmbpy = 5,5'-dimethyl-2,2'-bipyridine)

New bipyridine gold(III) dithiocarbamate-containing complexes exerted a potent anticancer activity against cisplatin-resistant cancer cells independent of p53 status.

Muhammad Altaf et al.

Oncotarget, 8(1), 490-505 (2016-11-27)

We synthesized, characterized and tested in a panel of cancer cell lines, nine new bipyridine gold(III) dithiocarbamate-containing complexes. In vitro studies demonstrated that compounds 1, 2, 4, 5, 7 and 8 were the most cytotoxic in prostate, breast, ovarian cancer

Syntheses of metallo-pseudorotaxanes, rotaxane and post-synthetically functionalized rotaxane: a comprehensive spectroscopic study and dynamic properties.

Saikat Santra et al.

Dalton transactions (Cambridge, England : 2003), 46(39), 13300-13313 (2017-08-05)

Herein, a bis-amido tris-amine macrocycle and five bipyridine-based bidentate chelating ligands were investigated towards various divalent transition metal ion (Ni

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5,5′-Dimethyl-2,2′-dipyridyl