543144

6-Chloro-1-hexene

96%

• Linear Formula: Cl(CH₂)₄CH=CH₂
• CAS Number: 928-89-2
• Molecular Weight: 118.60
• NACRES: NA.22
• PubChem Substance ID: 24878665
• UNSPSC Code: 12352100
• EC Number: 213-186-5
• MDL number: MFCD00039391
• Assay: 96%

Properties

• Quality Segment: 100
• assay: 96%
• refractive index: n20/D 1.438 (lit.)
• bp: 135-136 °C (lit.)
• density: 0.896 g/mL at 25 °C (lit.)
• functional group: alkyl halide, allyl, chloro
• SMILES string: ClCCCCC=C
• InChI: 1S/C6H11Cl/c1-2-3-4-5-6-7/h2H,1,3-6H2
• InChI key: BLMIXWDJHNJWDT-UHFFFAOYSA-N

Description

General description

6-Chloro-1-hexene is an ω-chloro-1-alkene. It reacts with β-substituted imines in the presence of a rhodium catalyst to afford tri- and tetra-substituted imines. It undergoes cross-coupling reaction in the presence of copper(II) chloride and 1-phenylpropyne.

Application

6-Chloro-1-hexene may be used in the synthesis of 1-(5-hexen)-2,3-dimethyl-imidazolium chloride.

Safety Information

• pictograms: GHS02,GHS07
• signalword: Warning
• hcodes: H226,H315,H319,H335
• pcodes: P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 3 - Flammable liquids
• wgk: WGK 3
• flash_point_f: 84.0 °F - closed cup
• flash_point_c: 28.9 °C - closed cup
• ppe: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter