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544760

Zirconium oxide

greener alternative

nanopowder, <100 nm particle size (TEM)

Synonym(s):

Nano zirconium oxide, Zirconium dioxide, Zirconium(IV) oxide, ZrO2 nanoparticles, Zirconia

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About This Item

Linear Formula:
ZrO2
CAS Number:
Molecular Weight:
123.22
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
215-227-2
MDL number:

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Product Name

Zirconium(IV) oxide, nanopowder, <100 nm particle size (TEM)

InChI key

MCMNRKCIXSYSNV-UHFFFAOYSA-N

InChI

1S/2O.Zr

SMILES string

O=[Zr]=O

form

nanopowder

reaction suitability

reagent type: catalyst
core: zirconium

Quality Level

mp

2700 °C (lit.)

density

5.89 g/mL at 25 °C (lit.)

greener alternative category

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

surface area

≥25 m2/g

particle size

<100 nm (TEM)

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1 of 4

This Item
2306936430251.00757
reaction suitability

reagent type: catalyst
core: zirconium

reaction suitability

reagent type: catalyst
core: zirconium

reaction suitability

reagent type: catalyst
core: zirconium

reaction suitability

-

form

nanopowder

form

powder

form

dispersion, nanoparticles

form

-

Quality Level

100

Quality Level

200

Quality Level

100

Quality Level

200

density

5.89 g/mL at 25 °C (lit.)

density

5.89 g/mL at 25 °C (lit.)

density

-

density

5.89 g/mL at 25 °C (lit.)

bp

5000 °C (lit.)

bp

5000 °C (lit.)

bp

-

bp

5000 °C (lit.)

mp

2700 °C (lit.)

mp

2700 °C (lit.)

mp

-

mp

2700 °C (lit.)

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. Zirconium(IV) oxide is a sustainable catalyst valued for its high thermal stability and eco-friendly nature. It efficiently promotes green chemical reactions such as hydrogenation and oxidation with high selectivity, enabling cleaner processes that reduce waste and energy consumption, thus supporting environmentally responsible industrial applications. Click here for more information.
Zirconium(IV) oxide (ZrO2) which is also known as zirconia is a ceramic nanoparticle that can be used as a nano-filler. It can be incorporated in a variety of polymer and metal composites to improve the thermo-mechanical properties of the base material.[1][2][3]

Application

ZrO2 can be used as a filler material on PMMA which can further be used as a high strength denture base material.[2][3] It can also be used as a composite based metallic coating that can improve the overall mechanical properties of the substrate.[4]

Storage Class

11 - Combustible Solids

wgk

nwg

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Friction and wear behavior of zirconium oxide reinforced PMMA composites
Akinci A, et al.
Composites Part B: Engineering, 56(1-2), 42-47 (2014)
Support and solvent effects on the liquid-phase chemoselective hydrogenation of crotonaldehyde over Pt catalysts
Hidalgo-Carrillo J, et al.
Applied Catalysis A: General, 385(1-2), 190-200 (2010)
Paolo Vigolo et al.
Journal of prosthodontics : official journal of the American College of Prosthodontists, 17(8), 621-626 (2008-09-19)
The purpose of this study was to assess in vitro the marginal fit of four-unit fixed partial dentures (FPDs) produced using three different computer aided design/computer aided manufacturing (CAD/CAM) all-ceramic systems before and after porcelain firing cycles and after glaze
Zhongpu Zhang et al.
Acta biomaterialia, 9(9), 8394-8402 (2013-05-21)
Effective and reliable clinical uses of dental ceramics necessitate an insightful analysis of the fracture behaviour under critical conditions. To better understand failure characteristics of porcelain veneered to zirconia core ceramic structures, thermally induced cracking during the cooling phase of
Katarzyna Zielińska et al.
Journal of colloid and interface science, 377(1), 362-367 (2012-04-14)
Ni-P-nano-ZrO(2) coatings were produced using the electroless deposition technique. To prevent agglomeration of zirconia nanoparticles in the plating bath, various surfactant additives (anionic, cationic, and nonionic) were used. The most stable bath was obtained with the addition of dodecyltrimethylammonium bromide

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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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