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545236

Sigma-Aldrich

Di-tert-butylsilane

97%

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$124.45

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5 ML
$124.45

About This Item

Linear Formula:
[(CH3)3C]2SiH2
CAS Number:
Molecular Weight:
144.33
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22

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$124.45

List Price$131.00
Web-Only Promotion

In StockDetails


Request a Bulk Order
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

Quality Level

assay

97%

refractive index

n20/D 1.42 (lit.)

bp

129-130 °C (lit.)

mp

−38 °C (lit.)

density

0.729 g/mL at 25 °C (lit.)

SMILES string

[H][Si]([H])(C(C)(C)C)C(C)(C)C

InChI

1S/C8H20Si/c1-7(2,3)9-8(4,5)6/h9H2,1-6H3

InChI key

ZLKSBZCITVUTSN-UHFFFAOYSA-N

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This Item
27613881101633941
assay

97%

assay

97%

assay

≥99.5% (GC)

assay

97% (CP)

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

-

density

0.729 g/mL at 25 °C (lit.)

density

0.789 g/mL at 25 °C (lit.)

density

0.726 g/mL at 25 °C (lit.)

density

0.829 g/mL at 25 °C (lit.)

mp

−38 °C (lit.)

mp

-

mp

−115 °C (lit.)

mp

-

refractive index

n20/D 1.42 (lit.)

refractive index

n20/D 1.447 (lit.)

refractive index

n20/D 1.401 (lit.)

refractive index

-

bp

129-130 °C (lit.)

bp

-

bp

88.8 °C (lit.)

bp

34-36 °C (lit.)

Application

Di-tert-butylsilane can be used as a reagent to synthesize:
  • 1,1-di-tert-butyl-N-phenylsilanamine by dehydrogenative coupling with aniline in the presence of supported gold catalyst.[1]
  • Benzyloxy di-tert-butylsilane by dehydrocoupling of benzyl alcohol using NaOH as a catalyst.[2]
  • Di-tert-butyl(3-cyclohexylprop-1-yn-1-yl)silane by silylation reaction with 2-propyn-1-ylcyclohexane using alkali metal hydroxide as a catalyst.[3]

pictograms

Flame

signalword

Danger

hcodes

Hazard Classifications

Flam. Liq. 2

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

28.0 °F - closed cup

flash_point_c

-2.22 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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