547824

Tris[N,N-Bis(trimethylsilyl)amide]gadolinium(III)

98%

• Synonym(s): Gadolinium bis(trimethylsilyl)amide, Gadolinium tris[bis(trimethylsilyl)amide]
• Linear Formula: Gd(N(Si(CH₃)₃)₂)₃
• CAS Number: 35789-03-8
• Molecular Weight: 638.40
• MDL number: MFCD03427091
• PubChem Substance ID: 24878983
• NACRES: NA.23

Properties

• Quality Level: 100
• Assay: 98%
• form: solid
• reaction suitability: core: gadolinium; reagent type: catalyst
• mp: 67-90 °C (lit.)
• SMILES string: C[Si](C)(C)N([Gd](N([Si](C)(C)C)[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C
• InChI: 1S/3C6H18NSi2.Gd/c3*1-8(2,3)7-9(4,5)6;/h3*1-6H3;/q3*-1;+3
• InChI key: LFWPRLGQJJEPDP-UHFFFAOYSA-N

Description

General description

Atomic number of base material: 64 Gadolinium

Application

In many asymmetric catalysis applications, glove box and Schlenk techniques should be employed to prevent exposure of the rare earth catalyst to air and moisture, which can be detrimental to the reaction outcome. Solutions of the catalyst should be made using anhydrous solvents and used shortly after preparation.

Safety Information

• Pictograms: GHS02,GHS05
• Signal Word: Danger
• Hazard Statements: H228 - H261 - H314
• Precautionary Statements: P210 - P231 + P232 - P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Flam. Sol. 1 - Skin Corr. 1B - Water-react 2
• Supplementary Hazards: EUH014
• Storage Class Code: 4.3 - Hazardous materials, which set free flammable gases upon contact with water
• WGK: WGK 3
• Flash Point(F): 36.0 °F - closed cup
• Flash Point(C): 2.2 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves