The 250 gram size is packaged in a single bag that is placed in a 1 gallon can. The 50 gram and 10 gram sizes are packaged in single amber glass bottles that are placed in an over pack can.
62420
Lithium aluminum hydride
≥97.0% (gas-volumetric)
Synonym(s):
LAH, Lithium alanate, Lithium tetrahydroaluminate
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About This Item
Linear Formula:
LiAlH4
CAS Number:
Molecular Weight:
37.95
EC Number:
MDL number:
UNSPSC Code:
26111700
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
assay
≥97.0% (gas-volumetric)
form
solid
reaction suitability
reagent type: reductant
mp
125 °C (dec.) (lit.)
SMILES string
[Li].[AlH3]
InChI
1S/Al.Li.4H/q-1;+1;;;;
InChI key
OCZDCIYGECBNKL-UHFFFAOYSA-N
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Related Categories
1 of 4
This Item | 323403 | 686034 | 199877 |
|---|---|---|---|
| assay ≥97.0% (gas-volumetric) | assay 95% | assay >99.95% | assay 95% |
| Quality Level 200 | Quality Level 200 | Quality Level 100 | Quality Level 200 |
| reaction suitability reagent type: reductant | reaction suitability reagent type: reductant | reaction suitability reagent type: reductant | reaction suitability reagent type: reductant |
| form solid | form pellets | form pellets | form powder |
| mp 125 °C (dec.) (lit.) | mp 125 °C (dec.) (lit.) | mp 125 °C (dec.) (lit.) | mp 125 °C (dec.) (lit.) |
General description
Lithium aluminum hydride (LiAlH4) is a powerful reducing agent used in organic synthesis to reduce esters, carboxylic acids, acyl chlorides, aldehydes, epoxides, and ketones into the corresponding alcohols. It also converts amide, nitro, nitrile, imine, oxime, and azide compounds into amines.[1]
Application
Reactant involved in:
Packaging
packed in plastic bag, which is soluble at 45-60°C in hydrocarbons, THF and dioxane
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1A - Water-react 1
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk_germany
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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Q. Chen, et al.,
Surface and Coating Tech., 205, 4418-4424 (2011)
R. A. Varin and L. Zbroniec,
J. Alloy Compounds, 509, S736-S739 (2011)
Chu Liang et al.
Nature communications, 12(1), 119-119 (2021-01-07)
Environmentally benign synthesis of graphite at low temperatures is a great challenge in the absence of transition metal catalysts. Herein, we report a green and efficient approach of synthesizing graphite from carbon dioxide at ultralow temperatures in the absence of
Rafi-ud-din, et al.,
The Journal of Physical Chemistry C, 115, 13088-13099 (2011)
Lithium Aluminum Hydride
Paquette LA, et al.
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2001)
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