631582

Sigma-Aldrich

(R)-(+)-2,2′-Bis(methoxymethoxy)-1,1′-binaphthalene

97%

Linear Formula:
(CH3OCH2OC10H6)2
CAS Number:
Molecular Weight:
374.43
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

97%

optical activity

[α]20/D +92°, c = 1% in chloroform

mp

101-105 °C (lit.)

SMILES string

COCOc1ccc2ccccc2c1-c3c(OCOC)ccc4ccccc34

InChI

1S/C24H22O4/c1-25-15-27-21-13-11-17-7-3-5-9-19(17)23(21)24-20-10-6-4-8-18(20)12-14-22(24)28-16-26-2/h3-14H,15-16H2,1-2H3

InChI key

YIAQRNNJNMLGTP-UHFFFAOYSA-N

Related Categories

Packaging

250 mg in amber glass bottle

Application

3- or 3,3′-di-substituted products can be obtained easily via ortho-metallation and subsequent treatment with an electrophile to give the corresponding BINOL derivatives.

Pictograms

CorrosionEnvironment

Signal Word

Danger

Hazard Statements

hazcat

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1

storage_class_code

13 - Non Combustible Solids

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

Certificate of Analysis

Certificate of Origin

Cox, P. J. et al
Tetrahedron Letters, 33, 2253-2253 (1992)
Articles
We present an article concerning BINOL and Derivatives.
Read More

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