637025

Cobalt(II,III) oxide

nanopowder, <50 nm particle size (TEM), 99.5% trace metals basis

• Synonym(s): Cobalt tetraoxide, Cobaltic-cobaltous oxide, Tricobalt tetraoxide
• Linear Formula: ~Co₃O₄
• CAS Number: 1308-06-1
• Molecular Weight: 240.80
• MDL number: MFCD00010939
• PubChem Substance ID: 24882820
• NACRES: NA.23

Properties

• Quality Level: 200
• Assay: 99.5% trace metals basis
• form: nanopowder
• particle size: <50 nm (TEM)
• surface area: BET surf. area 40-70 m²/g (typical range)
• mp: 895 °C (dec.) (lit.)
• density: 6.11 g/mL at 25 °C (lit.)
• bulk density: 0.57 g/mL
• application(s): battery manufacturing
• SMILES string: O=[Co].O=[Co]O[Co]=O
• InChI: 1S/3Co.4O
• InChI key: LBFUKZWYPLNNJC-UHFFFAOYSA-N

Description

General description

Cobalt oxide is a p-type semiconductor thatbelongs to the normal spinel crystal structure with cubic close packing ofoxide ions. It has variable oxidation states and multiple band gapenergies (2.28eV and 1.57eV). It is paramagnetic at room temperature.

Application

Cobalt(II,III) oxide nanoparticles can be used:

• To modify the glassycarbon electrode for the detection of As(III) at nanomolar concentrationrange.
• To prepare a robust photocatalyst along withcarbon nanospheres for dye degradation and hydrogen evolution reaction.
• As an electrodematerial in the preparation of supercapacitors.

Safety Information

• Pictograms: GHS08
• Signal Word: Danger
• Hazard Statements: H334 - H350i - H412
• Precautionary Statements: P201 - P202 - P261 - P273 - P304 + P340 + P312 - P308 + P313
• Hazard Classifications: Aquatic Chronic 3 - Carc. 1A Inhalation - Resp. Sens. 1
• Storage Class Code: 6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 1
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable