Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
638080
tBuXPhos
98%, solid
Synonym(s):
tBuXPhos, 2-Di-tert-butylphosphino-2′,4′,6′-triisopropylbiphenyl, t-Bu XPhos, tert-Butyl XPhos
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$47.18
List Price$59.20Save 20%In StockDetails
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About This Item
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$47.18
List Price$59.20Save 20%In StockDetails
Product Name
tBuXPhos, 98%
Quality Level
assay
98%
form
solid
reaction suitability
reaction type: Cross Couplings
reagent type: ligand
reaction type: Arylations
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reagent type: ligand
reaction type: Carboxylations
reagent type: ligand
reaction type: Decarboxylations
greener alternative product score
old score: 12
new score: 1
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greener alternative product characteristics
Atom Economy
Design for Energy Efficiency
Use of Renewable Feedstocks
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sustainability
Greener Alternative Product
mp
148-151 °C (lit.)
functional group
phosphine
greener alternative category
SMILES string
CC(P(C(C=CC=C1)=C1C(C(C(C)C)=CC(C(C)C)=C2)=C2C(C)C)C(C)(C)C)(C)C
InChI
1S/C29H45P/c1-19(2)22-17-24(20(3)4)27(25(18-22)21(5)6)23-15-13-14-16-26(23)30(28(7,8)9)29(10,11)12/h13-21H,1-12H3
InChI key
SACNIGZYDTUHKB-UHFFFAOYSA-N
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1 of 4
This Item | 901904 | 936693 | 638072 |
|---|---|---|---|
| reaction suitability reaction type: Cross Couplings, reagent type: ligand | reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst | reaction suitability - | reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand |
| assay 98% | assay 95% | assay - | assay 98% |
| form solid | form powder or crystals | form solid | form - |
| functional group phosphine | functional group phosphine | functional group - | functional group phosphine |
| Quality Level 300 | Quality Level - | Quality Level 100 | Quality Level 300 |
| mp 148-151 °C (lit.) | mp 148-151 °C (lit.), 150 °C | mp - | mp 164-166 °C (lit.) |
General description
Learn more about Buchwald Phosphine Ligands
Application
It can be used in the following reactions:
- Palladium-catalyzed Tsuji-Trost substitution and cross-coupling of benzylic fluorides.[2]
- Palladium-catalyzed C-N cross-coupling of sulfinamides and aryl halides.[3]
- Palladium-catalyzed rapid methoxylation and deuteriomethoxylation of bromo-chalcones.[4]
Legal Information
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdfHelpful?
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