638099
97%
reaction type: Cross Couplings
reagent type: ligand
reaction type: Arylations
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reagent type: ligand
reaction type: C-X Bond Formation
reagent type: ligand
reaction type: Hiyama Coupling
reagent type: ligand
reaction type: Methylations
reagent type: ligand
reaction type: Negishi Coupling
reagent type: ligand
reaction type: Oxidations
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling
102-106 °C (lit.)
phosphine
C1CCC(CC1)P(C2CCCCC2)c3ccccc3-c4ccccc4
1S/C24H31P/c1-4-12-20(13-5-1)23-18-10-11-19-24(23)25(21-14-6-2-7-15-21)22-16-8-3-9-17-22/h1,4-5,10-13,18-19,21-22H,2-3,6-9,14-17H2
LCSNDSFWVKMJCT-UHFFFAOYSA-N
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This Item | 638439 | 747807 | 900621 |
---|---|---|---|
reaction suitability reaction type: Cross Couplings, reagent type: ligand | reaction suitability reaction type: Cross Couplings, reagent type: ligand | reaction suitability - | reaction suitability - |
mp 102-106 °C (lit.) | mp 86-88 °C (lit.) | mp 178-183 °C (decomposition without melting) | mp - |
functional group phosphine | functional group phosphine | functional group phosphine | functional group phosphine |
Aquatic Chronic 4
11 - Combustible Solids
WGK 3
Not applicable
Not applicable
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The Pd-catalyzed C–N bond formation has become an important synthetic reaction in the past 20 years. Several research groups have investigated this reaction and developed very versatile catalysts. Buchwald and coworkers have been very active in synthesizing and developing a portfolio of phosphine ligands for this transformation and other cross-coupling reactions.
Buchwald Phosphine Ligands
Buchwald phosphine ligands for C-C, C-N, and C-O bond formation.
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