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MilliporeSigma

652571

N,N-Dimethylethylamine

≥99%

Synonym(s):

N-Ethyldimethylamine, DMEA

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500 ML

$176.00

2 L

$636.00

$176.00


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About This Item

Linear Formula:
(CH3)2NC2H5
CAS Number:
Molecular Weight:
73.14
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-940-8
Beilstein/REAXYS Number:
1696893
MDL number:
Assay:
≥99%

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InChI

1S/C4H11N/c1-4-5(2)3/h4H2,1-3H3

InChI key

DAZXVJBJRMWXJP-UHFFFAOYSA-N

SMILES string

CCN(C)C

vapor pressure

8.09 psi ( 20 °C)

assay

≥99%

refractive index

n20/D 1.372 (lit.)

bp

36-38 °C (lit.)

mp

−140 °C (lit.)

density

0.675 g/mL at 25 °C (lit.)

functional group

amine

Quality Level

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1 of 4

This Item
239356D982038.40018
assay

≥99%

assay

99%

assay

97%

assay

≥99.0% (GC)

Quality Level

100

Quality Level

200

Quality Level

200

Quality Level

200

bp

36-38 °C (lit.)

bp

36-38 °C (lit.)

bp

63-65 °C (lit.)

bp

36.5 °C/1013 hPa

density

0.675 g/mL at 25 °C (lit.)

density

0.675 g/mL at 25 °C (lit.)

density

0.72 g/mL at 25 °C (lit.)

density

0.675 g/cm3 at 20 °C

mp

−140 °C (lit.)

mp

−140 °C (lit.)

mp

-

mp

-140 °C

refractive index

n20/D 1.372 (lit.)

refractive index

n20/D 1.372 (lit.)

refractive index

n20/D 1.389 (lit.)

refractive index

-

Application

N,N-Dimethylethylamine (DMEA) is generally used to prepare water-soluble quaternary ammonium salts.[1] It facilitates lithium hexamethyldisilazide (LiHMDS) mediated enolization of highly substituted aryl ketones.[2][3] Additionally, DMEA is also used as an organic solvent in synthetic chemistry.[4][5]

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

Storage Class

3 - Flammable liquids

wgk

WGK 1

flash_point_f

-18.4 °F - closed cup

flash_point_c

-28 °C - closed cup

ppe

Faceshields, Gloves, Goggles


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Highly Stereoselective Synthesis of Tetrasubstituted Acyclic All-Carbon Olefins via Enol Tosylation and Suzuki-Miyaura Coupling.
Li BX, et al.
Journal of the American Chemical Society, 139(31), 10777-10783 (2017)
A theophylline based copper N-heterocyclic carbene complex: synthesis and activity studies in green media.
Szadkowska A, et al.
Royal Society of Chemistry Advances, 6(50), 44248-44253 (2016)
Lithium Hexamethyldisilazide-Mediated Enolization of Highly Substituted Aryl Ketones: Structural and Mechanistic Basis of the E/Z Selectivities.
Mack KA, et al.
Journal of the American Chemical Society, 139(35), 12182-12189 (2017)
Sodium Diisopropylamide in Tetrahydrofuran: Selectivities, Rates, and Mechanisms of Alkene Isomerizations and Diene Metalations.
Algera RF, et al.
Journal of the American Chemical Society, 139(33), 11544-11549 (2017)
Sodium Diisopropylamide in N, N-Dimethylethylamine: Reactivity, Selectivity, and Synthetic Utility.
Ma Y, et al.
The Journal of Organic Chemistry, 81(22), 11312-11315 (2016)

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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