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659711

Sigma-Aldrich

(R)-C3-TunePhos-ruthenium complex

All Photos(1)
Synonym(s):
[Chloro(R)-C3-TunePhos)(p-cymene)ruthenium(II)] chloride
Empirical Formula (Hill Notation):
C49H46Cl2O2P2Ru
CAS Number:
905709-79-7
Molecular Weight:
900.81
MDL number:
MFCD07782001
PubChem Substance ID:
24884439
NACRES:
NA.22

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Quality Level

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SMILES string

[Cl-].Cl[Ru+].C[C]1[CH][CH][C]([CH][CH]1)C(C)C.C2COc3cccc(P(c4ccccc4)c5ccccc5)c3-c6c(OC2)cccc6P(c7ccccc7)c8ccccc8

InChI

1S/C39H32O2P2.C10H14.2ClH.Ru/c1-5-16-30(17-6-1)42(31-18-7-2-8-19-31)36-26-13-24-34-38(36)39-35(41-29-15-28-40-34)25-14-27-37(39)43(32-20-9-3-10-21-32)33-22-11-4-12-23-33;1-8(2)10-6-4-9(3)5-7-10;;;/h1-14,16-27H,15,28-29H2;4-8H,1-3H3;2*1H;/q;;;;+2/p-2

InChI key

BOERIKXMDOKSHH-UHFFFAOYSA-L

Related Categories

Application

Chiral Quest Phosphine Ligands for Asymmetric Hydrogenation
Provides comparable or superior enantioselectivities and catalytic abilities to BINAP in Ru-catalyzed asymmetric hydrogenations of β-keto esters, cyclic β-(acylamino)acrylates and α-phthalimide ketones.

Packaging

100 mg in clear glass bottle
500 mg in amber glass bottle

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