666181
1,3-Dicyclohexylimidazolium tetrafluoroborate salt
97%, solid
Synonym(s):
1,3-Bis(cyclohexyl)imidazolium tetrafluoroborate
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| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 5 g | Check Cart for Availability | $572.00 $429.00 |
About This Item
Empirical Formula (Hill Notation):
C15H25BF4N2
CAS Number:
Molecular Weight:
320.18
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22
MDL number:
$429.00
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Product Name
1,3-Dicyclohexylimidazolium tetrafluoroborate salt, 97%
Quality Level
assay
97%
form
solid
reaction suitability
reagent type: ligand
mp
171-175 °C
SMILES string
F[B-](F)(F)F.C1CCC(CC1)n2cc[n+](c2)C3CCCCC3
InChI
1S/C15H25N2.BF4/c1-3-7-14(8-4-1)16-11-12-17(13-16)15-9-5-2-6-10-15;2-1(3,4)5/h11-15H,1-10H2;/q+1;-1
InChI key
CQHXJIHJFMBBQA-UHFFFAOYSA-N
Application
Used as organocatalyst in the catalytic boron conjugate additions to cyclic and acyclic unsaturated carbonyls[1]
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Kang-sang Lee et al.
Journal of the American Chemical Society, 131(21), 7253-7255 (2009-05-13)
Metal-free nucleophilic activation of a B-B bond has been exploited in the development of a highly efficient method for conjugate additions of commercially available bis(pinacolato)diboron to cyclic or acyclic alpha,beta-unsaturated carbonyls. The reactions are readily catalyzed by a simple N-heterocyclic
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 666181-5G | 04061833499610 |
| 666181-250MG | 04061833483626 |
| 666181-1G | 04061826724514 |