Key Documents

Bis[2-(N,N-dimethylamino)ethyl] ether

Name: Bis[2-(<I>N</I>,<I>N</I>-dimethylamino)ethyl] ether
Brand: ALDRICH
Price: 75.4 USD
Availability: InStock

97%

Synonym(s):

2,2′-Oxybis(N,N-dimethylethylamine), 2-(Dimethylamino)ethyl ether

Select a Size

Change View

Pack Size	SKU	Availability	Price
100 mL		Available to ship TODAYfromMILWAUKEE	$75.40
500 mL		Available to ship TODAYfromMILWAUKEE	$240.00

About This Item

Linear Formula:

((CH₃)₂N(CH₂CH₂))₂O

CAS Number:

3033-62-3

Molecular Weight:

160.26

NACRES:

NA.22

PubChem Substance ID:

24884926

UNSPSC Code:

12352100

EC Number:

221-220-5

MDL number:

MFCD00059199

Assay:

97%

$75.40

Available to ship TODAYDetails

One Time Order

Request a Bulk Order

Subscriptions are currently unavailable.

Technical Service

Need help? Our team of experienced scientists is here for you.

Let Us Assist

Properties

Quality Level

100

assay

97%

refractive index

n20/D 1.430

bp

189 °C/760 mmHg

density

0.841 g/mL at 25 °C

functional group

amine, ether

SMILES string

CN(C)CCOCCN(C)C

InChI

1S/C8H20N2O/c1-9(2)5-7-11-8-6-10(3)4/h5-8H2,1-4H3

InChI key

GTEXIOINCJRBIO-UHFFFAOYSA-N

Description

General description

2-(Dimethylamino)ethyl ether is a tridentate ligand. It assists in the formation and stabilization of intermediates during the exchange reactions.

Compare Similar Items

View Full Comparison

Show Differences

1 of 1

This Item	176095	226289	408980
Sigma-Aldrich 667609 Bis[2-(N,N-dimethylamino)ethyl] ether	Sigma-Aldrich 176095 2,2′-Oxydiethylamine dihydrochloride	Sigma-Aldrich 226289 N,N-Dimethyltrimethylsilylamine	Sigma-Aldrich 408980 2-(Diethylamino)ethyl methacrylate
assay 97%	assay 97%	assay 97%	assay 99%
Quality Level 100	Quality Level 200	Quality Level 200	Quality Level 100
density 0.841 g/mL at 25 °C	density -	density 0.732 g/mL at 25 °C (lit.)	density 0.922 g/mL at 25 °C (lit.)
refractive index n20/D 1.430	refractive index -	refractive index n20/D 1.397 (lit.)	refractive index n20/D 1.444 (lit.)
bp 189 °C/760 mmHg	bp -	bp 84 °C (lit.)	bp 80 °C/10 mmHg (lit.)
functional group amine, ether	functional group amine, ether	functional group amine	functional group -

pictograms

GHS06,GHS05

signalword

Danger

hcodes

H302 + H332,H311,H314

pcodes

P261 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

flash_point_f

151.0 °F

flash_point_c

66.11 °C

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Articles

Mild Mg – Halogen Exchange

Substantial progress has been made in magnesium–halogen exchange reactions used for the preparation of functionalized Grignard reagents containing sensitive moieties such as ester or cyano groups.

Bis[2-(dimethylamino)ethyl]ether(CH3)2NCH2CH2OCH2CH2N(CH3)2.

B Ballantyne

Journal of applied toxicology : JAT, 25(3), 260-269 (2005-04-28)

The acute toxicity and irritancy of bis[2-(dimethylamino)ethyl]ether.

B Ballantyne

Veterinary and human toxicology, 39(5), 290-295 (1997-10-06)

Bis[2-(dimethylamino)ethyl]ether (DMAEE; CAS No 3033-62-3) is an industrial liquid chemical used principally as an amine catalyst. It was investigated for potential acute hazards. DMAEE is of moderate acute peroral toxicity with LD50 values in the rat of 1045 ml/kg and

Highly catalytic asymmetric addition of deactivated alkyl grignard reagents to aldehydes.

Chao-Shan Da et al.

Organic letters, 11(24), 5578-5581 (2009-11-17)

Generally used and highly reactive RMgBr reagents were effectively deactivated by bis[2-(N,N-dimethylamino)ethyl] ether and then were employed in the highly enantioselective addition of Grignard reagents to aldehydes. The reaction was catalyzed by the complex of commercially available (S)-BINOL and Ti(O(i-)Pr)(4)

View All Related Papers

Global Trade Item Number

SKU	GTIN
667609-500ML	04061832734668
667609-100ML	04061832734651

Key Documents

Skip To

Bis[2-(N,N-dimethylamino)ethyl] ether

97%

Select a Size

About This Item

$75.40

Quality Level

assay

refractive index

bp

density

functional group

SMILES string

InChI

InChI key

General description

Compare Similar Items

This Item

Safety Information

pictograms

signalword

hcodes

pcodes

Hazard Classifications

Storage Class

flash_point_f

flash_point_c

ppe

Documentation

Certificates of Analysis (COA)

Already Own This Product?

Protocols and Articles

Articles

Peer Reviewed Papers

Global Trade Item Number

Key Documents

Skip To

Bis[2-(N,N-dimethylamino)ethyl] ether

97%

Select a Size

About This Item

667609-100ML

$75.40

Quality Level

assay

refractive index

bp

density

functional group

SMILES string

InChI

InChI key

General description

Compare Similar Items

This Item

Safety Information

pictograms

signalword

hcodes

pcodes

Hazard Classifications

Storage Class

flash_point_f

flash_point_c

ppe

Documentation

Certificates of Analysis (COA)

Already Own This Product?

Protocols and Articles

Articles

Peer Reviewed Papers

Global Trade Item Number