If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
671479
cataCXium® A
95%
Synonym(s):
Di(1-adamantyl)-n-butylphosphine
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$111.00
$438.00
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SMILES string
CCCCP([C@]12C[C@H]3C[C@H](C[C@H](C3)C1)C2)[C@@]45C[C@@H]6C[C@@H](C[C@@H](C6)C4)C5
assay
95%
reaction suitability
reagent type: ligand
reaction type: Arylations, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: C-C Bond Formation, reagent type: ligand
reaction type: Cross Couplings, reagent type: ligand
reaction type: Heck Reaction, reagent type: ligand
reaction type: Sonogashira Coupling, reagent type: ligand
reaction type: Suzuki-Miyaura Coupling
functional group
phosphine
Quality Level
Related Categories
1 of 4
This Item | 671800 | 671584 | 672343 |
|---|---|---|---|
| assay 95% | assay 95% | assay 95% | assay 95% |
| reaction suitability reagent type: ligand | reaction suitability - | reaction suitability - | reaction suitability - |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| functional group phosphine | functional group phosphine | functional group phosphine | functional group phosphine |
General description
Application
Other applications:
- palladium-catalyzed carbonylation of aryl and heteroaryl halides[5][6][7][8][9]
- palladium-catalyzed synthesis of (hetero)aromatic nitriles[10]
- palladium-catalyzed aminocarbonylation of aryl halides[11]
Features and Benefits
- Mild reaction condition
- Low catalyst loading
- High yield and turn over number
Legal Information
Storage Class
11 - Combustible Solids
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Articles
cataCXium® ligands facilitate cross-coupling reactions, essential in polymer science, fine chemicals, and pharmaceutical industries.
Related Content
Phosphine Ligand Application Guide
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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