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676578
Bis(tri-tert-butylphosphine)palladium(0)
solid
Synonym(s):
Pd(t-Bu3P)2
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About This Item
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Product Name
Bis(tri-tert-butylphosphine)palladium(0),
SMILES string
[Pd].CC(C)(C)P(C(C)(C)C)C(C)(C)C.CC(C)(C)P(C(C)(C)C)C(C)(C)C
InChI
1S/2C12H27P.Pd/c2*1-10(2,3)13(11(4,5)6)12(7,8)9;/h2*1-9H3;
InChI key
MXQOYLRVSVOCQT-UHFFFAOYSA-N
form
solid
reaction suitability
core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
greener alternative product characteristics
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
mp
258-272 °C
greener alternative category
, Aligned
storage temp.
−20°C
Quality Level
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1 of 4
This Item | |||
|---|---|---|---|
| reaction suitability core: palladium, reaction type: Cross Couplings, reaction type: Hiyama Coupling, reaction type: Sonogashira Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Negishi Coupling, reagent type: catalyst, reaction type: Stille Coupling, reaction type: Heck Reaction | reaction suitability core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst | reaction suitability core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst | reaction suitability core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst |
| form solid | form powder | form powder | form powder |
| Quality Level 100 | Quality Level 200 | Quality Level 100 | Quality Level 200 |
| storage temp. −20°C | storage temp. - | storage temp. - | storage temp. - |
| mp 258-272 °C | mp - | mp 131 °C (lit.) | mp - |
| greener alternative product characteristics Catalysis | greener alternative product characteristics Catalysis | greener alternative product characteristics Catalysis | greener alternative product characteristics Designing Safer Chemicals |
General description
Application
- Catalyst for Suzuki coupling on a multisubstituted sp3-carbon[1] (eq. 1)
- Catalyst for Stille coupling reaction of aryl chlorides[2] (eq. 2)
- Catalyst for Negishi coupling reaction[3] (eq. 3)
- Catalyst for Heck coupling to form tetrasubstituted olefins[4] (eq. 4)
- Catalyst for Buchwald-Hartwig amination of aryl halide[5] (eq. 5)
- Catalyst for carbonylation of aryl halides with carbamoylsilanes[6] (eq. 6)
On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
No data available
flash_point_c
No data available
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A variety of palladium-catalyzed cross-coupling reactions can be run under room temperature conditions in water with TPGS- 750-M, using a variety of commercially available palladium complexes and ligands.
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TPGS-750-M surfactant enables various reactions in water at room temperature, enhancing efficiency and versatility in synthesis.
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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