682314

(S)-N-Methyl-N-diphenylphosphino-1-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine

• Synonym(s): (1S)-1-(Diphenylphosphino)-2-[(1S)-1-[(diphenylphosphino)methylamino]ethyl]ferrocene, Methyl-BoPhoz
• Empirical Formula (Hill Notation): C₃₇H₃₅FeNP₂
• CAS Number: 406681-09-2
• Molecular Weight: 611.47
• MDL number: MFCD05865220
• PubChem Substance ID: 329760487

Properties

• form: solid
• Quality Level: 100
• mp: 104.1-109.2 °C
• SMILES string: [Fe].[CH]1[CH][CH][CH][CH]1.C[C@@H]([C]2[CH][CH][CH][C]2P(c3ccccc3)c4ccccc4)N(C)P(c5ccccc5)c6ccccc6
• InChI: 1S/C32H30NP2.C5H5.Fe/c1-26(33(2)35(29-20-11-5-12-21-29)30-22-13-6-14-23-30)31-24-15-25-32(31)34(27-16-7-3-8-17-27)28-18-9-4-10-19-28;1-2-4-5-3-1;/h3-26H,1-2H3;1-5H;/t26-;;/m1../s1
• InChI key: ZIAZHUWEJYUGEO-FBHGDYMESA-N

Description

Application

Methyl-BoPhoz can be used:

• As an efficient ligand for asymmetric hydrogenation reactions.
• To synthesize a single enantiomer of cyclopropylalanine via hydrogenation reaction using rhodium catalyst.
• To prepare chiral phenylalanine derivatives from α-amido cinnamic acids (or esters) using rhodium catalyst.

Legal Information

Sold in collaboration with Johnson Matthey Catalyst for research purposes only. US6590115 and any patents arising therefrom apply.

Safety Information

• Storage Class Code: 13 - Non Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable