This compound is listed as a Red to Brown to Red-Brown powder. While solubility testing is not performed on this product, the appearance of the solution is expected to be similar in color. Please see the link below to review a sample or lot specific Certificate of Analysis to review additional analytical information:
https://www.sigmaaldrich.com/product/aldrich/682500#product-documentation
682500
Copper(I) thiophene-2-carboxylate
Synonym(s):
(2-Thiophenecarboxylato)copper, 2-Thiophenecarboxylic acid, copper complex, Cu (TC), Cuprous 2-thiophenecarboxylate
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1 G
$146.00
$146.00
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About This Item
Empirical Formula (Hill Notation):
C5H3CuO2S
CAS Number:
Molecular Weight:
190.69
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
MDL number:
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InChI
1S/C5H4O2S.Cu/c6-5(7)4-2-1-3-8-4;/h1-3H,(H,6,7);/q;+1/p-1
SMILES string
[Cu]OC(=O)c1cccs1
InChI key
SFJMFSWCBVEHBA-UHFFFAOYSA-M
form
solid
reaction suitability
core: copper
reaction type: C-C Bond Formation
reagent type: catalyst
Quality Level
1 of 4
This Item | 283673 | 346276 | 734527 |
|---|---|---|---|
| reaction suitability core: copper, reagent type: catalyst, reaction type: C-C Bond Formation | reaction suitability core: copper, reagent type: catalyst | reaction suitability core: copper, reagent type: catalyst | reaction suitability core: copper, reagent type: catalyst |
| form solid | form - | form solid | form crystals |
| Quality Level 100 | Quality Level 200 | Quality Level 100 | Quality Level 100 |
Application
Copper(I) thiophene-2-carboxylate can be used as a reactant or reagent in:
- Studies of xenobiotic response to herbicide safener derivatives.[1]
- Synthesis of functionalized BODIPY dye analogs.[2]
- Orthogonal cross-coupling reactions.[3]
- Preparation of parent borondipyrromethene system.[4]
- Copper mediated cross-coupling.[5][6]
Reactant or reagent involved in:
- Studies of xenobiotic response to herbicide safener derivatives
- Synthesis of functionalized BODIPY dye analogs
- Orthogonal cross-coupling reactions
- Preparation of parent borondipyrromethene system
- Copper mediated cross-coupling
signalword
Warning
hcodes
pcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Xenobiotic responsiveness of Arabidopsis thaliana to a chemical series derived from a herbicide safener.
Skipsey M, et al.
The Journal of Biological Chemistry, 286(37), 32268-32276 (2011)
2?and 3?Monohalogenated BODIPY Dyes and Their Functionalized Analogues: Synthesis and Spectroscopy.
Leen V, et al.
European Journal of Organic Chemistry, 2011(23), 4386-4396 (2011)
Regioselective Syntheses of 2, 3?Substituted Pyridines by Orthogonal Cross?Coupling Strategies.
Koley M, et al.
European Journal of Organic Chemistry, 2011(10), 1972-1979 (2011)
N-Amidation by copper-mediated cross-coupling of organostannanes or boronic acids with O-acetyl hydroxamic acids.
Zhang Z, et al.
Organic Letters, 10(14), 3005-3008 (2008)
The smallest and one of the brightest. Efficient preparation and optical description of the parent borondipyrromethene system.
Arroyo I J, et al.
The Journal of Organic Chemistry, 74(15), 5719-5722 (2009)
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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