682705

Sigma-Aldrich

Chloro(tri-tert-butylphosphine)gold(I)

Synonym(s):
(Tri-tert-butylphosphine)gold(I) chloride, (Tri-tert-butylphosphine)chlorogold, (tBu3P)AuCl
Linear Formula:
(C4H9)3PAuCl
CAS Number:
Molecular Weight:
434.74
MDL number:
PubChem Substance ID:
Pricing and availability is not currently available.

Quality Level

reaction suitability

core: gold
reagent type: catalyst

mp

>300 °C

SMILES string

ClAu.CC(C)(C)P(C(C)(C)C)C(C)(C)C

InChI

1S/C12H27P.Au.ClH/c1-10(2,3)13(11(4,5)6)12(7,8)9;;/h1-9H3;;1H/q;+1;/p-1

InChI key

JLXSZGSXDDQSJF-UHFFFAOYSA-M

Application

Gold Catalysts — 21st Century ′Gold Rush′

  • Useful catalyst in a variety of C-C bond forming reactions, including cyclopropanation.

Packaging

1 g in glass bottle
250 mg in glass bottle

Pictograms

Skull and crossbones

Signal Word

Danger

Hazard Statements

Precautionary Statements

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

Hazard Codes

T

Risk Statement

25

Safety Statement

45

RIDADR

UN 2811 6.1 / PGIII

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis
Certificate of Origin
Toste, F.D. et al.
Journal of the American Chemical Society, 172, 18002-18002 (2005)

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