All Photos(1)

682942

Sigma-Aldrich

1,1′-Bis[(11bS)-dinaphtho[2,1-d:1′, 2′-f][1,3,2]dioxaphosphepin-4-yl]ferrocene

Synonym(s):
S,S-Reetz F-Diphosphonite
Empirical Formula (Hill Notation):
C50H32FeO4P2
CAS Number:
Molecular Weight:
814.58
MDL number:
PubChem Substance ID:

SMILES string

[Fe].[CH]1[CH][CH][C]([CH]1)P2Oc3ccc4ccccc4c3-c5c(O2)ccc6ccccc56.[CH]7[CH][CH][C]([CH]7)P8Oc9ccc%10ccccc%10c9-c%11c(O8)ccc%12ccccc%11%12

InChI

1S/2C25H16O2P.Fe/c2*1-5-11-20-17(7-1)13-15-22-24(20)25-21-12-6-2-8-18(21)14-16-23(25)27-28(26-22)19-9-3-4-10-19;/h2*1-16H;

InChI key

WMKZSCONNPWJGW-UHFFFAOYSA-N

Application

Used in a variety of asymmetric reactions, including: hydrogenations and conjugate additions.

Certificate of Analysis

Certificate of Origin

Reetz, M. T.
Pure and Applied Chemistry. Chimie Pure Et Appliquee, 71, 1503-1503 (1999)
Reetz, M. T. et al.
Chemical Communications (Cambridge, England), 2077-2077 (1998)

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