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683086

[Ir(cod)(acac)]

Umicore, crystals

Synonym(s):

(Acetylacetonato)(1,5-cyclooctadiene)iridium(I), Acetylacetonato(1,5-cyclooctadiene)iridium(I), Ir(acac)(COD)

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500 MG

$213.00

2 G

$646.00

$213.00

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About This Item

Empirical Formula (Hill Notation):
C13H19IrO2
CAS Number:
12154-84-6
Molecular Weight:
399.51
UNSPSC Code:
12161600
PubChem Substance ID:
329760791
NACRES:
NA.22
MDL number:
MFCD08273779

Key Documents

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Product Name

[Ir(cod)(acac)], Umicore

SMILES string

CC(=O)\C=C(\C)O[Ir].C1CC=CCCC=C1

InChI

1S/C8H12.C5H8O2.Ir/c1-2-4-6-8-7-5-3-1;1-4(6)3-5(2)7;/h1-2,7-8H,3-6H2;3,6H,1-2H3;/q;;+1/p-1/b2-1-,8-7-;4-3-;

InChI key

JHNBKYKCHXHKET-DWVXZKBMSA-M

form

crystals

reaction suitability

core: iridium, reagent type: catalyst

mp

150-155 °C (dec.)

Quality Level

100

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693774683094683183
[Ir(cod)(acac)] Umicore

Sigma-Aldrich

683086

[Ir(cod)(acac)]

Chiralyst P1271 Umicore

Sigma-Aldrich

693774

Chiralyst P1271

HS157 Umicore, 97%

Sigma-Aldrich

683094

HS157

CARAC Umicore, 98%

Sigma-Aldrich

683183

CARAC

reaction suitability

core: iridium, reagent type: catalyst

reaction suitability

core: iridium, reagent type: catalyst

reaction suitability

core: iridium, reaction type: C-H Activation, reagent type: catalyst

reaction suitability

core: rhodium, reagent type: catalyst

form

crystals

form

solid

form

powder

form

solid

Quality Level

100

Quality Level

100

Quality Level

200

Quality Level

100

mp

150-155 °C (dec.)

mp

-

mp

205 °C (dec.) (lit.)

mp

154-156 °C (lit.)

Application

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis
Precursor for Iridium complexes and catalysts

Legal Information

Product of Umicore

Additional information available at www.pmc.umicore.com

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCR3384
MKCQ1186
MKCL9311
MKCL0428
MKBW9309V

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G Sava et al.
Chemico-biological interactions, 45(1), 1-6 (1983-07-01)
The effects of square planar rhodium, [RhacacCOD]o and iridium, [IracacCOD]o complexes and of octahedral ruthenium, [cis-RuCl2 (DMSO)4]o complex have been examined in comparison with cis-dichlorodiammino platinum(II) (cis-PDD). The toxicity in BDF1 mice varies widely and decreasing LD50-values, ranging from 0.94

Articles

Umicore Precatalysts

Precatalysts for asymmetric catalysis offer batch-to-batch consistency in a range of catalytic reactions, supporting diverse research needs.

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