683094

HS157

Umicore, 97%

• Synonym(s): Bis(1,5-cyclooctadiene)diiridium(I) dichloride, [Ir(1,5-cod)Cl]2, 1,5-Cyclooctadiene-iridium(I) chloride dimer, Chloro(1,5-cyclooctadiene)iridium(I) dimer, Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]diiridium, Iridium(I) chloride 1,5-cyclooctadiene complex dimer, [Ir(1,5-cod)Cl]₂, [Ir(cod)Cl]2
• Empirical Formula (Hill Notation): C₁₆H₂₄Cl₂Ir₂
• CAS Number: 12112-67-3
• Molecular Weight: 671.70
• EC Number: 235-170-7
• MDL number: MFCD00012414
• PubChem Substance ID: 329760792
• NACRES: NA.22

Properties

• Quality Level: 200
• Assay: 97%
• form: powder
• reaction suitability: core: iridium; reaction type: C-H Activation; reagent type: catalyst
• mp: 205 °C (dec.) (lit.)
• SMILES string: Cl[Ir].Cl[Ir].C1CC=CCCC=C1.C2CC=CCCC=C2
• InChI: 1S/2C8H12.2ClH.2Ir/c2*1-2-4-6-8-7-5-3-1;;;;/h2*1-2,7-8H,3-6H2;2*1H;;/q;;;;2*+1/p-2/b2*2-1-,8-7-;;;;
• InChI key: ZFOUDQNHNLDNLD-MIXQCLKLSA-L

Description

Application

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

Metal precursor for asymmetric allylic substitutions.

Legal Information

Product of Umicore

Additional information available at www.pmc.umicore.com

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves