Absolutely. Please see the Technical Information for Download section (below) for additional examples of cross-coupling reactions involving the use of microwaves.
About This Item
form
pellets
matrix
Magnesium aluminometasilicate base material
SMILES string
[Fe].ClCCl.Cl[Pd]Cl.[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6
InChI
1S/2C17H14P.CH2Cl2.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;2-1-3;;;;/h2*1-14H;1H2;2*1H;;/q;;;;;;+2/p-2
InChI key
CWHRHCATIKFSND-UHFFFAOYSA-L
Legal Information
signalword
Warning
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Storage Class
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Can I use ChemDose® tablets in a microwave or pressure vessel?
1 answer-
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What is the pH stability of the ChemDose® tablets?
1 answer-
The ChemDose® tablets are mildly basic and will dissolve in the presence of mineral acids.
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What is the Department of Transportation shipping information for this product?
1 answer-
Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.
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How should I store ChemDose® tablets?
1 answer-
As with most catalysts and ligands, as a general precaution it is best to store them in a refrigerator and/or under an inert atmosphere to maintain activity. Some catalysts, such as Pd(dppf)Cl2·CH2Cl2, are more robust and can be handled in air without issue. Please refer to the ChemDose® label for specific handling of a given catalyst, ligand, or reagent.
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Do the ChemDose® tablets disintegrate during the course of the reaction?
1 answer-
They are normally recovered intact, however, they may disintegrate somewhat in aqueous reactions. Any disintegrated tablets can be removed from the reaction via filtration.
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Can I use ChemDose® tablets in any solvent?
1 answer-
Yes, including aqueous solvents.
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How should I dispose of spent ChemDose® tablets?
1 answer-
They should be treated as solid waste, contaminated with reaction species. The matrix is non-toxic and environmentally benign.
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