686891
Chiralyst P618
Umicore
Recommended Products
form
powder
reaction suitability
core: rhodium
reaction type: Cross Couplings
reagent type: catalyst
reaction type: C-H Activation
SMILES string
Cl[Rh]Cl.Cl[Rh]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C
InChI
1S/2C10H15.4ClH.2Rh/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q;;;;;;2*+2/p-4
InChI key
QNIVKTTWBMFSBR-UHFFFAOYSA-J
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This Item | 338370 | 683167 | 683175 |
|---|---|---|---|
| form powder | form solid | form powder | form solid |
| reaction suitability core: rhodium, reaction type: Cross Couplings, reagent type: catalyst | reaction suitability core: rhodium, reaction type: C-H Activation, reagent type: catalyst | reaction suitability core: rhodium, reagent type: catalyst | reaction suitability core: rhodium, reagent type: catalyst |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
Application
Catalyst for:
- Oxidative olefination reactions
- C-C bond cleavage of secondary alcohols
- Ortho C-H olefination of phenol derivatives
- Oxidative annulation of pyridines
- Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond
- Amidation reactions
- Reductive alkylation reactions
- The synthesis of multiaryl substituted naphthols via dual C-H bond functionalization of 2-aryloxypyridines.
- Regioselective C-N bond formation of azo compounds, wherein azide acts as a nitrogen source.
- Annulation of N-benzoylsulfonamide with isocyanide via C-H bond activation.
Legal Information
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Skin Irrit. 2
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
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