686891
Chiralyst P618
Umicore, powder
Synonym(s):
Pentamethylcyclopentadienylrhodium(III) chloride dimer, Di(μ-chloro)dichlorobis(pentamethylcyclopentadiene)dirhodium(III), 1,3-Cyclopentadiene, 1,2,3,4,5-pentamethyl-, rhodium complex, Bis(dichloro(pentamethylcyclopentadienyl)rhodium), Bis(pentamethylcyclopentadienylrhodium dichloride), Dichloro(pentamethylcyclopentadienyl)rhodium(II) dimer, Tetrachlorobis(pentamethylcyclopentadienyl)dirhodium
Select a Size
$393.00
$1,110.00
$393.00
About This Item
Skip To
Product Name
Chiralyst P618, Umicore
SMILES string
Cl[Rh]Cl.Cl[Rh]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C
InChI
1S/2C10H15.4ClH.2Rh/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q;;;;;;2*+2/p-4
InChI key
QNIVKTTWBMFSBR-UHFFFAOYSA-J
form
powder
reaction suitability
core: rhodium
reaction type: Cross Couplings
reagent type: catalyst
reaction type: C-H Activation
Quality Level
Looking for similar products? Visit Product Comparison Guide
1 of 4
This Item | 683167 | 683213 | 683132 |
|---|---|---|---|
| reaction suitability core: rhodium, reagent type: catalyst | reaction suitability core: rhodium, reagent type: catalyst | reaction suitability core: ruthenium, reaction type: Cross Couplings, reagent type: catalyst | reaction suitability core: rhodium, reaction type: Cross Couplings, reagent type: catalyst |
| form powder | form powder | form powder | form crystals |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
Application
Catalyst for:
- Oxidative olefination reactions
- C-C bond cleavage of secondary alcohols
- Ortho C-H olefination of phenol derivatives
- Oxidative annulation of pyridines
- Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond
- Amidation reactions
- Reductive alkylation reactions
- The synthesis of multiaryl substituted naphthols via dual C-H bond functionalization of 2-aryloxypyridines.[1]
- Regioselective C-N bond formation of azo compounds, wherein azide acts as a nitrogen source.[2]
- Annulation of N-benzoylsulfonamide with isocyanide via C-H bond activation.[3]
Legal Information
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Skin Irrit. 2
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Articles
Precatalysts for asymmetric catalysis offer batch-to-batch consistency in a range of catalytic reactions, supporting diverse research needs.
Active Filters
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Contact Technical Service