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For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf
688096
Tris[2-phenylpyridinato-C2,N]iridium(III)
97%
Synonym(s):
Ir(ppy)3, Iridium, tris[2-(2-pyridinyl-κN)phenyl-κC]
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$416.00
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$416.00
In StockDetails
description
fac-Tris[2-phenylpyridinato-C2,N]iridium(III)
Quality Level
assay
97%
form
powder
reaction suitability
core: iridium
reaction type: Photocatalysis
reagent type: catalyst
photocatalyst activation
425 nm
fluorescence
λex 340 nm; λem 512 nm in chloroform
orbital energy
HOMO 5.6 eV
LUMO 3 eV
OLED device performance
ITO/HMPD/TAZ:Ir(ppy)3 (7%)/Alq3/Al:Li
- Color: green
- Max. Luminance: 4000 Cd/m2
- Max. EQE: 15 %
ITO/NPD/CBP:Ir(ppy)3 (6%)/Alq3/Mg:Ag
- Color: green
- Max. Luminance: 100000 Cd/m2
- Max. EQE: 8 %
- Turn-On Voltage: 4.3 V
ITO/NPD/TCTA/BCPO:Ir(ppy)3 (7-8%)/BCP/Alq3/LiF/Al
- Color: green
- Max. Luminance: 207839 Cd/m2
- Max. EQE: 21.6 %
- Turn-On Voltage: 2.1 V
ITO/TCTA/Ir(ppy)3/Bphen/LiF/Al
- Color: green
- Max. Luminance: 300000 Cd/m2
- Max. EQE: 19 %
- Turn-On Voltage: 2.6 V
SMILES string
c1ccc(nc1)-c2ccccc2[Ir](c3ccccc3-c4ccccn4)c5ccccc5-c6ccccn6
InChI
1S/3C11H8N.Ir/c3*1-2-6-10(7-3-1)11-8-4-5-9-12-11;/h3*1-6,8-9H;
InChI key
QKBWDYLFYVXTGE-UHFFFAOYSA-N
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Related Categories
1 of 4
This Item | 694924 | 932744 | 682594 |
|---|---|---|---|
| description fac-Tris[2-phenylpyridinato-C2,N]iridium(III) | description - | description - | description - |
| assay 97% | assay - | assay ≥99% (HPLC) | assay 96% |
| form powder | form powder | form - | form powder |
| reaction suitability core: iridium | reaction suitability - | reaction suitability - | reaction suitability - |
| photocatalyst activation 425 nm | photocatalyst activation - | photocatalyst activation - | photocatalyst activation - |
| fluorescence λex 340 nm; λem 512 nm in chloroform | fluorescence λex 305 nm; λem 507 nm in chloroform | fluorescence λem 514 nm±10 nm in dichloromethane | fluorescence λem 480 nm in chloroform |
General description
Application
Engaging unactivated alkyl, alkenyl and aryl iodides in visible-light-mediated free radical reactions
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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